Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)-Cu(OAc)2 • H2O complex

被引：81

作者：

Ginotra, Sandeep K. ^{[1
]}

Singh, Vinod K. ^{[1
]}

机构：

[1] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2007年 / 5卷 / 24期

关键词：

D O I：

10.1039/b714153j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A C-2-symmetric diethyl Pr-i-bis( oxazoline)-Cu(OAc)2 center dot H2O was found to be an efficient catalyst for catalyzing an enantioselective Henry reaction between nitromethane and various aldehydes to provide beta-hydroxy nitroalkanes with high chemical yields ( up to 95%) and enantiomeric excesses ( up to 97%).

引用

页码：3932 / 3937

页数：6

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