Enantioselective Henry reaction catalyzed by a C2-symmetric bis(oxazoline)-Cu(OAc)2 • H2O complex

被引：81
|
作者：
Ginotra, Sandeep K. [1 ]
Singh, Vinod K. [1 ]
机构：
[1] Indian Inst Technol Kanpur, Dept Chem, Kanpur 208016, Uttar Pradesh, India
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2007年 / 5卷 / 24期
关键词：
D O I：
10.1039/b714153j
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A C-2-symmetric diethyl Pr-i-bis( oxazoline)-Cu(OAc)2 center dot H2O was found to be an efficient catalyst for catalyzing an enantioselective Henry reaction between nitromethane and various aldehydes to provide beta-hydroxy nitroalkanes with high chemical yields ( up to 95%) and enantiomeric excesses ( up to 97%).
引用
收藏
页码：3932 / 3937
页数：6
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