Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) pyridine disolvate

被引:1
作者
Khaledi, Hamid [1 ]
Ali, Hapipah Mohd [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
D O I
10.1107/S1600536811001991
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The Pd-II ion in the title compound, [Pd(C17H14N3S2)(2)]center dot 2C(5)H(5)N, is located on an inversion center and is four-coordinated by two of the deprotonated N,S-bidentate Schiff base ligands in a square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 71.12 (9)degrees. The indole NH groups are bonded to the pyridine solvent molecules via an N-H center dot center dot center dot N interaction. The crystal structure is consolidated by intermolecular C-H center dot center dot center dot S interactions.
引用
收藏
页码:M230 / U1122
页数:9
相关论文
共 7 条
[1]  
Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189, DOI [DOI 10.1016/S1472-7862(02)00030-8, 10.1016/S1472-7862(02)00030-8]
[2]  
Bruker, 2007, APEX2 SAINT
[3]   Bis{benzyl 3-[(1H-indol-3-yl)methylidene]dithiocarbazato-κ2N3,S}palladium(II) N,N-dimethylformamide disolvate [J].
Khaledi, Hamid ;
Ali, Hapipah Mohd .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :M84-U905
[4]   Coordination behavior of three geometric isomers of indole-based S-benzyldithiocarbazone ligands towards nickel, zinc and cadmium divalent ions [J].
Khaledi, Hamid ;
Ali, Hapipah Mohd ;
Olmstead, Marilyn M. .
INORGANICA CHIMICA ACTA, 2011, 366 (01) :233-240
[5]  
Sheldrick G.M., 1996, SADABS
[6]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122
[7]   publCIF: software for editing, validating and formatting crystallographic information files [J].
Westrip, Simon P. .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925