An Organometallic Future in Green and Energy Chemistry?

被引：144

作者：

Crabtree, Robert H. ^{[1
]}

机构：

[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 01期

关键词：

IRIDIUM COMPLEXES; CATALYTIC-SYSTEM; DEHYDROGENATION; OXIDATION; EFFICIENT; ALCOHOLS; AMMONIA; AMINES; BORANE; WATER;

D O I：

10.1021/om1009439

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title topic is reviewed with selected examples taken from recent work, such as: the 'hydrogen borrowing' amine alkylation by alcohols; the dehydrogenative coupling of amine and alcohol to give amide; Ru complexes as solar cell photosensitizers; Ir organometallics as water oxidation catalyst precursors and as OLED emitters; as well as recent hydrogen storage strategies involving catalytic dehydrogenation of ammonia-borane and of organic heterocycles.

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页码：17 / 19

页数：3

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