Ruthenium-catalyzed asymmetric hydrosilylation of ketones and imine

被引：169
|
作者：
Nishibayashi, Y
Takei, I
Uemura, S [1 ]
Hidai, M
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan
[2] Univ Tokyo, Dept Chem & Biotechnol, Grad Sch Engn, Tokyo 1138656, Japan
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 16期
关键词：
D O I：
10.1021/om980399o
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ruthenium complexes with (oxazolinylferrocenyl)phosphines, RuCl2(PPh3)((oxazolinylferrocenyl)-phosphine), have been prepared and characterized by spectroscopy. these ruthenium complexes are very effective catalysts for asymmetric hydrosilylation of not only ketones but also an imine to give the corresponding sec-alcohols (up to 97% ee) and a sec-amine (88% ee) after acid hydrolysis, respectively.
引用
收藏
页码：3420 / 3422
页数：3
相关论文
共 50 条
  • [1] Ruthenium-catalyzed asymmetric transfer hydrogenation of ketones in ethanol
    Lundberg, Helena
    Adolfsson, Hans
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [2] Ruthenium-catalyzed asymmetric transfer hydrogenation of ketones in ethanol
    Lundberg, Helena
    Adolfsson, Hans
    TETRAHEDRON LETTERS, 2011, 52 (21) : 2754 - 2758
  • [3] Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation of Propargylic Ketones
    Shatskiy, Andrey
    Kivijarvi, Tove
    Lundberg, Helena
    Tinnis, Fredrik
    Adolfsson, Hans
    CHEMCATCHEM, 2015, 7 (23) : 3818 - 3821
  • [4] Ruthenium-Catalyzed Hydrosilylation of Aldehydes with Hydrooligosilanes
    Kanno, Ken-ichiro
    Sunaga, Yasuhiro
    Kyushin, Soichiro
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2024, 650 (22):
  • [5] Use of the Trost Ligand in the Ruthenium-Catalyzed Asymmetric Hydrogenation of Ketones
    Cettolin, Mattia
    Puylaert, Pim
    Pignataro, Luca
    Hinze, Sandra
    Gennari, Cesare
    de Vries, Johannes G.
    CHEMCATCHEM, 2017, 9 (16) : 3125 - 3130
  • [6] Asymmetric hydrosilylation of ketones catalyzed by ruthenium complexes with chiral tridentate ligands
    Zhu, G.
    Terry, M.
    Zhang, X.
    Journal of Organometallic Chemistry, 547 (01):
  • [7] Asymmetric hydrosilylation of ketones catalyzed by ruthenium complexes with chiral tridentate ligands
    Zhu, GX
    Terry, M
    Zhang, XM
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 547 (01) : 97 - 101
  • [8] Bis-paracyclophane NHC-ruthenium-catalyzed asymmetric hydrosilylation of ketones
    Song, C
    Ma, YD
    Andrus, MB
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U204 - U204
  • [9] Highly Efficient and Chemoselective Ruthenium-Catalyzed Hydrosilylation of Aldehydes
    Do, Youngshil
    Han, Junghoon
    Rhee, Young Ho
    Park, Jaiwook
    ADVANCED SYNTHESIS & CATALYSIS, 2011, 353 (18) : 3363 - 3366
  • [10] Ruthenium-catalyzed hydrosilylation of C=N bond in benzothiazole
    Kucinski, Krzysztof
    Hreczycho, Grzegorz
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 846 : 321 - 325
12345