Dual emission from a family of conjugated dinuclear RuII complexes

被引：88

作者：

Glazer, EC ^{[1
]}

Magde, D ^{[1
]}

Tor, Y ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 12期

关键词：

D O I：

10.1021/ja0440304

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dual emission is observed from a family of simple acetylene-linked dinuclear RuII complexes, where two MLCT excited states coexist at room temperature and in fluid solution. This unique behavior is attributed to a specific substitution pattern on the bridging ligand and provides the opportunity to investigate the structural and electronic features that result in decoupling of standard nonradiative decay pathways. Copyright © 2005 American Chemical Society.

引用

页码：4190 / 4192

页数：3

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