Coupling reaction in catalytic decomposition of cyclohexyl hydroperoxide

被引：6

作者：

Zheng, Xi ^{[1
]}

Ma, Jiping ^{[1
]}

Wang, Min ^{[1
]}

Shi, Song ^{[1
]}

Sun, Zhiqiang ^{[1
]}

Xu, Jie ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 101卷

基金：

中国国家自然科学基金;

关键词：

Cyclohexyl hydropemdde; Decomposition; Oxidation; Coupling reaction; AEROBIC OXIDATION; COMPLEXES; DEPEROXIDATION; PORPHYRINS; DINUCLEAR; LIGHT;

D O I：

10.1016/j.catcom.2017.07.030

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Coupling reaction of cyclohexyl hydroperoxide (CHHP) decomposition and cyclohexane oxidation in the process of catalytic decomposition of CHHP was identified via cyclopentane instead of cyclohexane used as solvent. A method was established to evaluate this coupling reaction. Based on this method, it can be accurately distinguished the product of cyclohexanol and cyclohexanone (K/A oil) derived from whether decomposition of CHHP or oxidation of cyclohexane. The established method is of great significance to the further study of the coupling reaction.

引用

页码：77 / 80

页数：4

共 29 条

[1] Mn porphyrins immobilized on non-modified and chloropropyl-functionalized mesoporous silica SBA-15 as catalysts for cyclohexane oxidation [J].

Araujo Pinto, Victor Hugo ;

Reboucas, Julio Santos ;

Ucoski, Geani Maria ;

de Faria, Emerson Henrique ;

Ferreira, Breno Freitas ;

Silva San Gil, Rosane Aguiar ;

Nakagaki, Shirley .

APPLIED CATALYSIS A-GENERAL, 2016, 526 :9-20

[2] Design of bifunctionalized hexagonal mesoporous silicas for selective oxidation of cyclohexane [J].

Chen, Chen ;

Zhou, Lipeng ;

Zhang, Qiaohong ;

Ma, Hong ;

Miao, Hong ;

Xu, Jie .

NANOTECHNOLOGY, 2007, 18 (21)

[3] Direct Synthesis of Bifunctionalized Hexagonal Mesoporous Silicas and Its Catalytic Performance for Aerobic Oxidation of Cyclohexane [J].

Chen, Chen ;

Xu, Jie ;

Zhang, Qiaohong ;

Ma, Hong ;

Miao, Hong ;

Zhou, Lipeng .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (07) :2855-2860

[4]

Constantini M., 1989, US Patent, Patent No. [4,918,238, 4918238, 4 918 238]

[5]

Costantini M., 1986, Eur. Patent., Patent No. 0270468

[6] Catalytic oxidation of cyclohexane to KA oil by zinc oxide supported manganese 5,10,15,20-tetrakis(4-nitrophenyl)porphyrin [J].

Feng, Ze ;

Xie, Yujia ;

Hao, Fang ;

Liu, Pingle ;

Luo, He'an .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2015, 410 :221-225

[7] DECOMPOSITION OF CYCLOHEXYL HYDROPEROXIDE CATALYZED BY RUTHENIUM PORPHYRINS - HYDROXYLATION OF THE SOLVENT CYCLOHEXANE [J].

HANSEN, CB ;

AGTERBERG, FPW ;

VANEIJNDHOVEN, AMC .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 102 (03) :117-128

[8] Autoxidation of cyclohexane: Conventional views challenged by theory and experiment [J].

Hermans, I ;

Nguyen, TL ;

Jacobs, PA ;

Peeters, J .

CHEMPHYSCHEM, 2005, 6 (04) :637-645

[9] One-pot room-temperature conversion of cyclohexane to adipic acid by ozone and UV light [J].

Hwang, Kuo Chu ;

Sagadevan, Arunachalam .

SCIENCE, 2014, 346 (6216) :1495-1498

[10] Mild peroxidative oxidation of cyclohexane catalyzed by mono-, di-, tri-, tetra- and polynuclear copper triethanolamine complexes [J].

Kirillov, AM ;

Kopylovich, MN ;

Kirillova, MV ;

Karabach, YY ;

Haukka, M ;

da Silva, MFCG ;

Pombeiro, AJL .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (1-2) :159-174

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