The sorption behavior of Cs + ion on clay minerals and zeolite in radioactive waste management: sorption kinetics and thermodynamics

被引:72
|
作者
Yildiz, B. [1 ]
Erten, H. N. [2 ]
Kis, M. [1 ]
机构
[1] Hacettepe Univ, Dept Chem, Fac Sci, TR-06532 Ankara, Turkey
[2] Bilkent Univ, Dept Chem, Fac Sci, TR-06533 Ankara, Turkey
关键词
Clay; Bentonite; Zeolite; Radioactive waste; AQUEOUS-SOLUTIONS; NATURAL ZEOLITES; BENTONITE; REMOVAL; CESIUM; MONTMORILLONITE; ADSORPTION; KAOLINITE; CEMENT;
D O I
10.1007/s10967-011-0990-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work, Cs+ ion sorption on some clays and zeolite were investigated. Cs-137 was used as a tracer. Activities were measured with a NaI crystal gamma counter. The particle size distribution was determined by a laser sizer. Surface area of the particles were determined by BET (Brunauer, Emmett and Teller method). Structure analysis was made by using X-ray diffraction. The chemical compositions of the solid samples were determined using a ICAP-OE spectrometer. Kinetic and thermodynamic parameters were determined. Due to very high uptake results; clay and zeolite can be proposed as a good sorbents in waste management considerations.
引用
收藏
页码:475 / 483
页数:9
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