C72Cl4: A Pristine Fullerene with Favorable Pentagon-Adjacent Structure

被引：43

作者：

Tan, Yuan-Zhi

Zhou, Ting

Bao, Jian

Shan, Gui-Juan

Xie, Su-Yuan ^{[1
]}

Huang, Rong-Bin

Zheng, Lan-Sun

机构：

[1] Xiamen Univ, Coll Chem & Chem Engn, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 48期

关键词：

CAGE; METALLOFULLERENE; STABILIZATION; LA-2-AT-C-72; ENERGY; CARBON; C-50; C-72; C-60;

D O I：

10.1021/ja108860y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A long-sought empty non-IPR fullerene, C-#11188(72), which is more stable than the sole IPR isomer in the fullerene[72] family, has been retrieved and crystallographically characterized as (C72Cl4)-C-#11188. Mass spectrometric data support the facile dechlorination of (C72Cl4)-C-#11188 and, in turn, the possible stability of pristine C-#11188(72).

引用

页码：17102 / 17104

页数：3

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