Activity stabilization of Ga-MFI zeolite catalyst modified by chemical vapor deposition

被引：2

作者：

Bhat, YS ^{[1
]}

Das, J ^{[1
]}

Halgeri, AB ^{[1
]}

机构：

[1] INDIAN PETROCHEM CORP LTD, RES CTR, BARODA 391345, GUJARAT, INDIA

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1996年 / 69卷 / 02期

关键词：

D O I：

10.1246/bcsj.69.469

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemical vapor deposition of silica on Ga-MFI zeolite was carried out using tetraethyl orthosilicate. The enhancement in para selectivity during toluene alkylation with the extent of silica deposition was closely monitored. The effect of reaction temperature on the behavior of silica deposited Ga-MFI zeolite was established. A deactivation trend in toluene conversion was observed when the zeolite was employed for alkylation for longer periods. The reasons for catalytic deactivation and stability enhancement by in situ coking are discussed.

引用

页码：469 / 472

页数：4

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