Palladium-catalyzed synthesis of allylic thioacetates. A convenient access to allylic thiols

被引：20
作者：
Divekar, S
Safi, M
Soufiaoui, M
Sinou, D
机构：
[1] Univ Lyon 1, CPE Lyon, CNRS, Lab Synthese, F-69622 Villeurbanne, France
[2] Fac Sci & Tech, Cite Yasmina, Mohammedia, Morocco
[3] Univ Mohamed V, Fac Sci, Rabat, Morocco
来源：
TETRAHEDRON | 1999年 / 55卷 / 14期
关键词：
palladium; alkylation; potassium thioacetate; allylic thioester;
D O I：
10.1016/S0040-4020(99)00129-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium(0)-catalyzed alkylation of various allylic acetates and carbonates by potassium thioacetate allowed an easy access to allylic thioacetates in rather good yields. The reaction was regioselective with substitution at the less hindered side of the intermediate pi-allyl system, and diastereoselective with net retention of configuration. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：4369 / 4376
页数：8
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