Y(NO3)3•6H2O catalyzed aza-Michael addition of aromatic/hetero-aromatic amines under solvent-free conditions

被引：65

作者：

Bhanushali, Mayur J. ^{[1
]}

Nandurkar, Nitin S. ^{[1
]}

Jagtap, Sachin R. ^{[1
]}

Bhanage, Bhalchandra M. ^{[1
]}

机构：

[1] Univ Bombay, Dept Chem, Inst Chem Technol Autonomous, Bombay 400019, Maharashtra, India

来源：

CATALYSIS COMMUNICATIONS | 2008年 / 9卷 / 06期

关键词：

aza-Michael; yttrium(III) nitrate hexahydrate; solvent-free; amines; N-heterocycles;

D O I：

10.1016/j.catcom.2007.11.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The aza-Michael addition of weakly nucleophilic amines with alpha, beta-unsaturated compounds like esters, nitriles and amides has been carried out efficiently using Y(NO3)(3)center dot 6H(2)O as a novel catalyst under solvent-free conditions. The catalyst exhibited remarkable activity and the methodology was applicable to a wide variety of aryl/hetero-aryl amines having different steric and electronic properties giving high yields of desired adducts at ambient conditions. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：1189 / 1195

页数：7

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