Pressure-induced metallization and structural transition of rhombohedral Se

被引:5
|
作者
Kawamura, H [1 ]
Matsui, N
Nakahata, I
Nakano, K
Kobayashi, M
Akahama, Y
Nagata, K
Miyamoto, Y
机构
[1] Himeji Inst Technol, Fac Sci, Kamigohri, Hyogo 6781297, Japan
[2] Fukuoka Univ, Fac Sci, Jonan Ku, Fukuoka 8140133, Japan
关键词
X-ray scattering; phase transition;
D O I
10.1016/S0038-1098(98)00418-9
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Powder X-ray diffraction experiments and electrical resistance measurements were performed at pressures up to 22 GPa for rhombohedral Se consisting of cyclic Se-6 molecules. Pressure-induced metallization was observed at a pressure around 16 GPa, accompanied by a structural phase transition. The critical pressure of metallization for rhombohedral Se is higher than that for alpha-monoclinic Se (12 GPa) and lower than that for trigonal Se (23 GPa). (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:677 / 680
页数:4
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