C-H Bonds Phosphorylation of Ketene Dithioacetals

被引：55

作者：

Zhu, Liping ^{[1
]}

Yu, Hongmei ^{[1
]}

Guo, Quanping ^{[1
]}

Chen, Qiao ^{[1
]}

Xu, Zhaoqing ^{[1
]}

Wang, Rui ^{[1
,2
]}

机构：

[1] Lanzhou Univ, Sch Basic Med Sci, Key Lab Preclin Study New Drugs Gansu Prov, Lanzhou 730000, Peoples R China

[2] Hong Kong Polytech Univ, State Key Lab Chirosci, Hong Kong, Hong Kong, Peoples R China

来源：

ORGANIC LETTERS | 2015年 / 17卷 / 08期

关键词：

PALLADIUM-CATALYZED PHOSPHONATION; PHOSPHINE OXIDES; MULTISUBSTITUTED OLEFINS; SELECTIVE SYNTHESIS; ARYLBORONIC ACIDS; ALKENES; ARYL; CONSTRUCTION; 1,1-DIBROMO-1-ALKENES; TRIFLUOROMETHYLATION;

D O I：

10.1021/acs.orglett.5b00728

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

C-H bond phosphorylation of ketene dithioacetals was achieved under transition-metal-free or AgNO3 mediated conditions. Synthetic transformations of the coupling product provided promising methods for the construction of highly functionalized phosphorylated N-heterocycles and tetrasubstituted alkenes.

引用

页码：1978 / 1981

页数：4

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