Synthesis, characterization, crystal structure, and hybrid DFT computation of antimony(III) chloride diazide, SbCl(N3)2

被引：0

作者：

Klapötke, TM ^{[1
]}

Nöth, H ^{[1
]}

Schütt, T ^{[1
]}

Warchold, M ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2001年 / 627卷 / 01期

关键词：

antimony; azides; crystal structure; hybrid DFT;

D O I：

10.1002/1521-3749(200101)627:1<81::AID-ZAAC81>3.0.CO;2-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

SbCl(N-3)(2) was synthesized by the reaction of two equivalents of sodium azide with SbCl3 in CH2Cl2. The structure of the compound was determined by X-ray structure determination. SbCl(N-3)(2) crystallizes in the monoclinic space group C2/c with a = 11.694(4), b = 7.751(4) and c = 12.241(5) Angstrom, beta = 100.45(1)degrees, with 8 formula units per unit cell. The SbCl(N-3)(2) molecules show interactions to form chains. The frequencies obtained by Raman and infrared spectroscopy were assigned to the normal modes of the SbCl(N-3)(2) molecules in comparison with computational results.

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页码：81 / 84

页数：4

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