Phosphinous Acid Platinum Complex as Robust Catalyst for Oxidation: Comparison with Palladium and Mechanistic Investigations

被引：6

作者：

Membrat, Romain ^{[1
]}

Vasseur, Alexandre ^{[1
]}

Martinez, Alexandre ^{[1
]}

Giordano, Laurent ^{[1
]}

Nuel, Didier ^{[1
]}

机构：

[1] Aix Marseille Univ, CNRS, Cent Marseille, iSm2,UMR 7313, F-13397 Marseille, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 2018卷 / 39期

关键词：

P ligands; Hydrides; Palladium; Platinum; Oxidation; Hydrogen transfer; STERICALLY HINDERED AMINES; NUCLEAR-MAGNETIC-RESONANCE; AEROBIC OXIDATION; SELECTIVE OXIDATION; OXO COMPLEXES; REACTIVITY; ALCOHOLS; HYDROXO; BINUCLEAR; STABILITY;

D O I：

10.1002/ejoc.201801040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Secondary phosphine oxides proved to be effective preligands to stabilise a hydroxy-platinum based catalyst that allows the aerobic/anaerobic oxidation of challenging substrates. Kinetic comparisons showed that this system is more efficient and stable than previously reported similar palladium-based catalysts. A neutral platinum dimer bearing bridging hydroxy ligands has been isolated and fully characterised by X-ray diffraction and its involvement in the mechanism has been evidenced by mechanistic studies.

引用

页码：5427 / 5434

页数：8

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