Solvent extraction of zinc from zinc sulfate solution

被引：19

作者：

Long Huai-zhong ^{[1
]}

Chai Li-yuan ^{[1
]}

Qin Wen-qing ^{[2
]}

Tang Shuang-hua ^{[2
]}

机构：

[1] Cent S Univ, Sch Met Sci & Engn, Changsha 410083, Hunan, Peoples R China

[2] Cent S Univ, Sch Resources Proc & Bioengn, Changsha 410083, Hunan, Peoples R China

来源：

JOURNAL OF CENTRAL SOUTH UNIVERSITY OF TECHNOLOGY | 2010年 / 17卷 / 04期

基金：

中国国家自然科学基金;

关键词：

zinc sulfate solution; saponified bi(2-ethylhexyl) phosphoric acid (D2EHPA); zinc; solvent extraction; D2EHPA;

D O I：

10.1007/s11771-010-0553-x

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

The extraction of zinc from zinc sulfate solution was investigated, using 20% saponified D2EHPA as an extractant and 260(#) sulfonate kerosene as a diluent. The solution was stirred for 8 min at phase ratio (V (o)/V (a)) of 1.0:1.0, initial pH of 2.0 and stirring speed of 200 r/min. The results show that 75% zinc can be extracted from the zinc sulfate solution when the concentration of zinc is 18.7 g/L after being settled for 10 min. 88.60% zinc can be stripped by 196 g/L sulfuric acid, and zinc ion can be separated from ferric ion.

引用

页码：760 / 764

页数：5

共 15 条

[1]

[陈浩 Chen Hao], 2003, [有色金属, Nonferrous metals], V55, P50

[2] Solvent extraction of zinc from ammoniacal/ammonium chloride solutions by a sterically hindered β-diketone and its mixture with tri-n-octylphosphine oxide [J].

Fu, Weng ;

Chen, Qiyuan ;

Wu, Qian ;

Hu, Huiping ;

Bai, Lan .

HYDROMETALLURGY, 2010, 100 (3-4) :116-121

[3]

GAO ZL, 1991, SOLVENT EXTRACTION C, P66

[4] Preliminary design of a solvent extraction process for the galvanic stripping of iron from D2EHPA [J].

Gu, H ;

Chang, CM ;

Barrera-Godínez, JA ;

O'Keefe, TJ .

MINERALS & METALLURGICAL PROCESSING, 2000, 17 (01) :16-22

[5]

LAN XH, 2008, WORLD NONFERROUS MET, P28

[6]

LAN XH, 2007, WORLD NONFERROUS MET, P20

[7]

LIU G, 2005, HYDROMETALLURGY CHIN, V24, P221

[8]

MA RJ, 1979, RES PROGR SOLVENT EX, P227

[9] The solvent extraction of zinc, cadmium and chromium from phosphoric acid solutions by tri-n butyl phosphate in kerosene diluent [J].

Mellah, Abdelhamid ;

Benachour, Djafer .

SEPARATION AND PURIFICATION TECHNOLOGY, 2007, 56 (02) :220-224

[10] Simulated small-scale pilot plant heap leaching of low-grade oxide zinc ore with integrated selective extraction of zinc [J].

Qin, Wen-qing ;

Li, Wei-zhong ;

Lan, Zhuo-yue ;

Qiu, Guan-zhou .

MINERALS ENGINEERING, 2007, 20 (07) :694-700

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