New semiconducting core-shell nanocomposites

被引:17
作者
Al-Hussaini, A. S. [1 ]
El-Bana, W. E. [1 ]
El-Ghamaz, N. A. [2 ]
机构
[1] Port Said Univ, Fac Sci, Chem Dept, 23 December St, Port Said 42521, Egypt
[2] Damietta Univ, Fac Sci, Phys Dept, Dumyat, Egypt
关键词
Polycondensation; gamma-nano-Al2O3; core-shell; semiconductive polymer nanocomposites; TEM; antimicrobial activity; NONCONVENTIONAL SYNTHESIS; ELECTRICAL-PROPERTIES; ANTHRANILIC ACID; POLYANILINE; FABRICATION; PARTICLES; TERPOLY(ANILINE; NANOPARTICLES; COMPOSITES; COPOLYMER;
D O I
10.1080/09276440.2019.1637237
中图分类号
TB33 [复合材料];
学科分类号
摘要
The present work describes a remarkable synthetic interest of semiconducting core-shell nanocomposites (CSNCs) contained aluminum oxide. Al2O3@poly(aniline -co- o-phenylenediamine) (Al2O3@PANI-o-PDA) CSNCs were fabricated by fivefold molar ratio of the appropriate moieties with various quantities of gamma-Al2O3 by oxidative polymerization. The formation of the Al2O3@PANI-o-PDA CSNCs was confirmed by spectral characteristics. The nanocomposite core-shell feature was found cores thickness 38 nm and shells thickness 41-44 nm. The recorded sigma(dc) is 2.9 x 10(-8)-1.45 x 10(-7) ohm(-1) m(-1) being in the range of semiconductor materials at room temperature and increases with increasing temperature. The newly fabricated materials were investigated as antimicrobial agents. The setup presents a facile, cheap, novel and beneficial methodology to develop novel CSNCs acquiring the required numerous functionality.
引用
收藏
页码:385 / 399
页数:15
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