Naphthalimide Modified Rhodamine Derivative: Ratiometric and Selective Fluorescent Sensor for Cu2+ Based on Two Different Approaches

被引：313
作者：
Zhang, Jun Feng [1 ,3 ]
Zhou, Ying [2 ]
Yoon, Juyoung [2 ]
Kim, Youngmee [2 ]
Kim, Sung Jin [2 ]
Kim, Jong Seung [1 ]
机构：
[1] Korea Univ, Dept Chem, Seoul 130701, South Korea
[2] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea
[3] Yunnan Normal Univ, Coll Chem & Chem Engn, Kunming 650092, Peoples R China
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 17期
关键词：
OFF-ON; AQUEOUS-SOLUTION; CHEMODOSIMETER; CHEMOSENSOR; CU(II); ION; FLUOROIONOPHORE;
D O I：
10.1021/ol101535s
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new rhodamine-based derivative bearing a 1,8-naphthalimide group (1) was synthesized as a dual-mode Cu2+-selective sensor via the rhodamine ring-opening approach and ratiometric displacement. A colorimetric and "off on" signal for Cu2+ through rhodamine ring opening in 1 and ratiometric fluorescent signal output when Cu2+ displaces the bound Zn2+ in the 1-Zn2+ complex can be observed.
引用
收藏
页码：3852 / 3855
页数：4
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