Synthesis and Structural Characterization of Manganese(II), Iron(III), Cobalt(II) and Copper(II) Complexes of 3-[1-(3,4-Dihydro-6-methyl-2,4-dioxo-2H-pyran-3-yl)ethylideneamino]-benzoic Acid

被引：0
|
作者：
Mane, V. G. [1 ]
机构：
[1] Jawahar Arts Sci & Commerce Coll, Dept Chem, Tuljapur 413603, Osmanabad, India
来源：
ASIAN JOURNAL OF CHEMISTRY | 2011年 / 23卷 / 03期
关键词：
Schiff bases; Dehydroacetic acid; m-Aminobenzoic acid; Metal complexes; SCHIFF-BASES; DEHYDROACETIC ACID; METAL-COMPLEXES; ANTIBACTERIAL; NICKEL(II); ZINC(II);
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The solid complexes of Mn(II), Fe(III), Co(II) and Cu(II) with Schiff base derived from 3-acetyl-6-methyl-(2H)-pyran-2,4(3H)dione (dehydroacetic acid) and m-aminobenzoic acid have been synthesized and characterized by elemental analysis, conductometry, thermal analysis, magnetic, IR, UV-vis and NMR spectral studies. From the analytical and thermal data, the stoichiometry of the complexes has been found to be 1:2 (metal:ligand). The low conductance values suggest that the complexes are non-electrolyte. IR spectral data suggest that the ligand behaves as a dibasic bidentate ligand with N:O donor sequence towards metal ions. The physico-chemical data suggests that all the complexes possess octahedral geometry. They are also screened for antimicrobial activity.
引用
收藏
页码：1065 / 1068
页数：4
相关论文
共 50 条
  • [21] COMPLEXES OF 4-METHOXY-2-(5-METHOXY-3-METHYL-PYRAZOL-1-YL)-6-METHYL-PYRIMIDINE COMPLEXES OF COBALT(II) NICKEL(II) COPPER(II) AND ZINC(II)
    MOLLA, MC
    GARCIA, J
    BORRAS, J
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1985, 15 (05): : 553 - 561
  • [22] Synthesis and characterization of chromium(III), manganese(II), iron(III), cobalt(II), nickel(II), copper(II), zinc(II), mercury(II), ruthenium(III), rhodium(III), platinum(IV) and gold(III) complexes with 1-(2'-pyridyl)benzothiazole-2-thione
    Khan, TA
    Shahjahan
    Zaidi, SAA
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1997, 36 (02): : 153 - 156
  • [23] Synthesis and characterization of 4-aminocinnolin-3-carboxylic acid and 4-amino-6-fluoro-7-chlorocinnolin-3-carboxylic acid complexes with cobalt (II), nickel (II), copper (II) and iron (II)
    Manohara, YN
    Nayak, PV
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1997, 27 (04): : 589 - 599
  • [24] SYNTHESIS AND CHARACTERIZATION OF CHROMIUM(III), COBALT(II), MANGANESE(II), NICKEL(II) AND COPPER(II) COMPLEXES WITH 3-HYDRAZINO-5,6-DIPHENYL-1,2,4-TRIAZINE
    HADI, AKA
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1994, 33 (09): : 879 - 881
  • [25] Synthesis, spectral and antibacterial activity of Co(II), Ni(II) and Zn(II) complexes with 2-hydroxy-benzoic acid(3,4-dihydro-2H-naphthalen-1-ylidene)-hydrazide
    Tyagi, Monika
    Tyagi, Prateek
    Chandra, Sulekh
    APPLIED ORGANOMETALLIC CHEMISTRY, 2017, 31 (12)
  • [26] Electrochemical Properties of 3-(3,5-Dimethylpyrazol-1-yl)-6-R-1,2,4,5-tetrazines and Their Complexes with Copper(II), Cobalt(II), and Nickel(II)
    Dyakonova, E. V.
    Buldakova, L. Y.
    Yanchenko, M. Y.
    Polyakov, E. V.
    Ishmetova, R. I.
    Rusinov, G. L.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2023, 93 (SUPPL 1) : S277 - S284
  • [27] Electrochemical Properties of 3-(3,5-Dimethylpyrazol-1-yl)-6-R-1,2,4,5-tetrazines and Their Complexes with Copper(II), Cobalt(II), and Nickel(II)
    E. V. Dyakonova
    L. Y. Buldakova
    M. Y. Yanchenko
    E. V. Polyakov
    R. I. Ishmetova
    G. L. Rusinov
    Russian Journal of General Chemistry, 2023, 93 : S277 - S284
  • [28] Synthesis and Reactivity of 1-[(2-methoxy)benzene]-3-[benzothiazole]Triazene With Copper(II) or Cobalt(II) Chloride
    Lv, Qi-ying
    Li, Wei
    Zhan, Shu-zhong
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (05) : 764 - 769
  • [29] Synthesis, structure and property of cobalt(II) complexes with 3,5-di(1H-imidazol-1-yl)benzoic acid
    Su, Zhi
    Bai, Zheng-Shuai
    Xu, Jing
    Okamura, Taka-aki
    Liu, Guang-Xiang
    Chu, Qian
    Wang, Xiao-Feng
    Sun, Wei-Yin
    Ueyama, Norikazu
    CRYSTENGCOMM, 2009, 11 (05): : 873 - 880
  • [30] Synthesis, spectroscopic, crystal structure and DNA binding of Ru(II) complexes with 2-hydroxy-benzoic acid [1-(4-hydroxy-6-methyl-2-oxo-2H-pyran-3-yl)-ethylidene]-hydrazide
    Chitrapriya, Nataraj
    Kamatchi, Thangavel Sathiya
    Zeller, Matthias
    Lee, Hyosun
    Natarajan, Karuppannan
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2011, 81 (01) : 128 - 134
12345