The effect of plasma treatment on the surface chemistry and structure of ZnMgAl coatings

被引:11
作者
Duchoslav, J. [1 ,2 ]
Kehrer, M. [2 ,3 ]
Truglas, T. [4 ]
Groiss, H. [4 ]
Nadlinger, M. [1 ]
Hader-Kregl, L. [1 ]
Riener, C. K. [5 ]
Arndt, M. [5 ]
Stellnberger, K. H. [5 ]
Luckeneder, G. [5 ]
Angeli, G. [5 ]
Stehrer, T. [3 ]
Stifter, D. [2 ]
机构
[1] Kompetenzzentrum Elektrochem Oberflachentechnol G, Viktor Kaplan Stra ss 2, A-2700 Wiener Neustadt, Austria
[2] Johannes Kepler Univ Linz, Ctr Surface & Nanoanalyt ZONA, Altenberger Str 69, A-4040 Linz, Austria
[3] Fronius GmbH, Gunter Fronius Str, A-4600 Thalheim Bei Wels, Austria
[4] Johannes Kepler Univ Linz, Christian Doppler Lab Nanoscale Phase Transformat, Ctr Surface & Nanoanalyt, Altenberger Str 69, A-4040 Linz, Austria
[5] Voestalpine Stahl GmbH, Voestalpine Str 3, A-4031 Linz, Austria
关键词
ZnMgAl coating; Plasma treatment; XPS; AES; TEM; ZN-AL-MG; DIP GALVANIZED STEEL; X-RAY PHOTOELECTRON; COATED STEEL; IN-SITU; ATMOSPHERIC CORROSION; ELECTRON-SPECTROSCOPY; SODIUM-CHLORIDE; MAGNESIUM; ALLOYS;
D O I
10.1016/j.apsusc.2019.144457
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A principal investigation on the effect of atmospheric pressure plasma on Zn1.5Mg2.5Al coating was performed by means of X-ray photoelectron- and Auger electron spectroscopy as well as by transmission electron microscopy. The type of the medium used to generate the plasma influenced significantly the impact of the proceeded treatment. Although a mild surface cleaning and oxidation effect was observed for air, N-2 or H2O plasma, mixed air + H2O and N-2 + H2O plasma types already caused a remarkable altering of the chemical composition, structure and thickness of the coating surface layer, a similar effect to an initial corrosion attack.
引用
收藏
页数:11
相关论文
共 55 条
[1]   Nanoscale surface analysis on second generation advanced high strength steel after hot dip galvanizing [J].
Arndt, M. ;
Duchoslav, J. ;
Preis, K. ;
Samek, L. ;
Stifter, D. .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2013, 405 (22) :7119-7132
[2]   Nanoscale analysis of surface oxides on ZnMgAl hot-dip-coated steel sheets [J].
Arndt, M. ;
Duchoslav, J. ;
Itani, H. ;
Hesser, G. ;
Riener, C. K. ;
Angeli, G. ;
Preis, K. ;
Stifter, D. ;
Hingerl, K. .
ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2012, 403 (03) :651-661
[3]  
Arrowsmith D.J., 1985, INT J ADH, V5, P40
[4]   Corrosion mechanisms of Zn(Mg,Al) coated steel: 2. The effect of Mg and Al alloying on the formation and properties of corrosion products in different electrolytes [J].
Azevedo, M. Salgueiro ;
Allely, C. ;
Ogle, K. ;
Volovitch, P. .
CORROSION SCIENCE, 2015, 90 :482-490
[5]   Corrosion mechanisms of Zn(Mg, Al) coated steel in accelerated tests and natural exposure: 1. The role of electrolyte composition in the nature of corrosion products and relative corrosion rate [J].
Azevedo, M. Salgueiro ;
Allely, C. ;
Ogle, K. ;
Volovitch, P. .
CORROSION SCIENCE, 2015, 90 :472-481
[6]  
Beamson G., 1998, HIGH RESOLUTION XPS
[7]   Corrosion of wire arc sprayed ZnMgAl [J].
Bobzin, K. ;
Oete, M. ;
Linke, T. F. ;
Schulz, C. .
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2015, 66 (06) :520-526
[8]  
Briggs D., 1998, SURFACE ANAL POLYM X
[9]   Surface analysis of unsized and sized carbon fibers [J].
Dilsiz, N ;
Wightman, JP .
CARBON, 1999, 37 (07) :1105-1114
[10]   A model for plasma modification of polypropylene using atmospheric pressure discharges [J].
Dorai, R ;
Kushner, MJ .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (06) :666-685