Efficient One-Pot Synthesis of Water-Compatible Molecularly Imprinted Polymer Microspheres by Facile RAFT Precipitation Polymerization

被引：180

作者：

Pan, Guoqing ^{[1
]}

Zhang, Ying ^{[1
]}

Ma, Yue ^{[1
]}

Li, Chenxi ^{[1
]}

Zhang, Huiqi ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Key Lab Funct Polymer Mat, Minist Educ, Tianjin 300071, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 49期

基金：

中国国家自然科学基金;

关键词：

molecular recognition; polymers; polymerization; RAFT; water compatible; SELECTIVE RECOGNITION; BLOCK-COPOLYMERS; BINDING-SITES; RECEPTORS; DRUG; ANTIBODIES; REMOVAL; MIMICS;

D O I：

10.1002/anie.201104751

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Narrowly dispersed water-compatible molecularly imprinted polymer (MIP) microspheres with surface-grafted hydrophilic polymer brushes were synthesized by RAFT precipitation polymerization (RAFTPP) mediated by hydrophilic macromolecular chain-transfer agents (Macro-CTA). The easy availability of hydrophilic Macro-CTAs and the versatility of the RAFTPP technique make it a general and promising strategy. CDB=cumyl dithiobenzoate. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：11731 / 11734

页数：4

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