Preparation of biotin derivatives by catalytic oxidative carbonylation of diamines

被引：4
作者：
Zhang, Y [1 ]
Forinash, K
Phillips, CR
McElwee-White, L
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[2] Univ Florida, Ctr Catalysis, Gainesville, FL 32611 USA
来源：
GREEN CHEMISTRY | 2005年 / 7卷 / 06期
关键词：
D O I：
10.1039/b500197h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Biotin methyl ester and related heterocyclic ureas were synthesized by W(CO) 6-catalyzed oxidative carbonylation of the corresponding diamines. This procedure provides an alternative to the use of phosgene and phosgene derivatives for formation of the urea moiety.
引用
收藏
页码：451 / 455
页数：5
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