Effect of Protonated Organic Cations and Anion-π Interactions on the Magnetic Behavior of Hexabromorhenate(IV) Salts

被引：23

作者：

Martinez-Lillo, Jose ^{[1
]}

Pedersen, Anders H. ^{[1
]}

Faus, Juan ^{[2
]}

Julve, Miguel ^{[2
]}

Brechin, Euan K. ^{[1
]}

机构：

[1] Univ Edinburgh, EaStCHEM Sch Chem, Edinburgh EH9 3FJ, Midlothian, Scotland

[2] Univ Valencia, Inst Ciencia Mol ICMol, Dept Quim Inorgan, Valencia 46980, Spain

来源：

CRYSTAL GROWTH & DESIGN | 2015年 / 15卷 / 06期

基金：

英国工程与自然科学研究理事会;

关键词：

X-RAY-STRUCTURE; COMPLEXES;

D O I：

10.1021/acs.cgd.5b00436

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel Re-IV compounds of formula (Hbpym)(2)[(ReBr6)-Br-IV]center dot 4H(2)O (1) and (H(4)biim)[(ReBr6)-Br-IV]center dot 4H(2)O (2) [Hbpym(+) = 2,2'-bipyrimidinium cation and H(4)biim(2+) = 2,2'-biimidazolium dication] have been prepared and magnetostructurally characterized. 1 and 2 exhibit distinct crystal packing, and the presence of weak intermolecular contacts, such as Re-Br...B-rRe (1 and 2), Re-Br center dot center dot center dot(H2O)center dot center dot center dot BrRe (1 and 2), and Re-Br center dot center dot center dot pi center dot center dot center dot Br-Re (2), lead to different magnetic behaviors. While 1 is antiferromagnetic, 2 is a ferromagnetic compound and indeed the first example of ferromagnetic salt based on the hexabromorhenate(IV) anion. These results suggest a straightforward synthetic route to the preparation of new ferromagnetically coupled Re-IV compounds.

引用

页码：2598 / 2601

页数：4

共 25 条

[1] Hexachlororhenate(IV) salts of ruthenium(III) cations: X-ray structure and magnetic properties [J].

Armentano, Donatella ;

Martinez-Lillo, Jose .

INORGANICA CHIMICA ACTA, 2012, 380 :118-124

[2] On the Importance of Anion-π Interactions in the Mechanism of Sulfide:Quinone Oxidoreductase [J].

Bauza, Antonio ;

Quinonero, David ;

Deya, Pere M. ;

Frontera, Antonio .

CHEMISTRY-AN ASIAN JOURNAL, 2013, 8 (11) :2708-2713

[3] 2,2'-Bi(1H-imidazolium) dichloride [J].

Belanger, S ;

Beauchamp, AL .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 :2588-2590

[4]

Carlin R. L., 1986, MAGNETOCHEMISTRY

[5] The π-Accepting Arene HAT(CN)6 as a Halide Receptor through Charge Transfer: Multisite Anion Interactions and Self-Assembly in Solution and the Solid State [J].

Chifotides, Helen T. ;

Schottel, Brandi L. ;

Dunbar, Kim R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (40) :7202-7207

[6] Encapsulation of anions: Macrocyclic receptors based on metal coordination and anion-π interactions [J].

Frontera, Antonio .

COORDINATION CHEMISTRY REVIEWS, 2013, 257 (11-12) :1716-1727

[7] Putting Anion-π Interactions Into Perspective [J].

Frontera, Antonio ;

Gamez, Patrick ;

Mascal, Mark ;

Mooibroek, Tiddo J. ;

Reedijk, Jan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (41) :9564-9583

[8] The anion-π interaction: naissance and establishment of a peculiar supramolecular bond [J].

Gamez, Patrick .

INORGANIC CHEMISTRY FRONTIERS, 2014, 1 (01) :35-43

[9] Hexachlororhenate(IV) salts of organic radical cations [J].

González, R ;

Romero, F ;

Luneau, D ;

Armentano, D ;

De Munno, G ;

Kremer, C ;

Lloret, F ;

Julve, M ;

Faus, J .

INORGANICA CHIMICA ACTA, 2005, 358 (13) :3995-4002

[10] Magnetic studies on hexahalorhenate(IV) salts of ferrocenium cations [Fe(C5R5)2]2[ReX6] (R = H, CH3; X = Cl, Br, I) [J].

González, R ;

Chiozzone, R ;

Kremer, C ;

Guerra, F ;

De Munno, G ;

Lloret, F ;

Julve, M ;

Faus, J .

INORGANIC CHEMISTRY, 2004, 43 (09) :3013-3019

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