Blue luminescent zinc(II) complexes of 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine and 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine

被引：20

作者：

Fan, RQ ^{[1
]}

Zhu, DS ^{[1
]}

Ding, H ^{[1
]}

Mu, Y ^{[1
]}

Su, Q ^{[1
]}

Xia, H ^{[1
]}

机构：

[1] Jilin Univ, Sch Chem, Key Lab Supramol Struct & Mat, Minist Educ, Changchun 130012, Peoples R China

来源：

SYNTHETIC METALS | 2005年 / 149卷 / 2-3期

基金：

中国国家自然科学基金;

关键词：

bis(imino)pyridyl ligands; zinc complexes; crystal structure; blue luminescence;

D O I：

10.1016/j.synthmet.2004.12.016

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Two new Zn(II) complexes of, 2,6-bis[1-(2,6-diisopropylphenylimino)ethyl]pyridine (L-1), 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine (L-2) were synthesized. These two complexes have the formulas Zn(L-1)Cl-2 (1) and Zn(L-2)(Cl2CH3CN)-C-. (2), respectively. Crystal structures of complexes 1 and 2 were determined by single-crystal X-ray diffraction. Crystallographic studies on I and 2 reveal both complexes to be five-coordinate with geometries that can be best described as distorted trigonal bipyramidal. Complexes 1 and 2 have blue luminescence at room temperature in solution and the solid state. The blue luminescence of the complexes is due to pi* -> pi* Tr transition centered on the ligands. The Zn(II) centers play a key role in enhancing fluorescent emission of the ligands. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：135 / 141

页数：7

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