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Volumetric Properties for Binary Mixtures of Nonane plus Decane at Temperatures from T=283.15 to 353.15 K and at p=0.7 atm
被引:7
作者:
Zuniga-Moreno, Abel
[1
]
Reza-San German, Carmen M.
[1
]
Rojas-Valencia, Oscar G.
[1
]
Juarez-Camacho, Elizabeth P.
[1
]
机构:
[1] Inst Politecn Nacl, Dept Ingn Quim Ind, Escuela Super Ingn Quim & Ind Extract, UPALM, Mexico City, DF, Mexico
关键词:
Decane;
Density;
Excess molar volume;
Nonane;
Partial molar volume;
Redlich-Kister expansion;
MINOR CONSTITUENT FLUIDS;
EXCESS MOLAR VOLUMES;
N-OCTANE;
KINEMATIC VISCOSITIES;
LIQUID SYSTEMS;
NATURAL-GAS;
DENSITIES;
HEPTANE;
DEPENDENCE;
D O I:
10.1007/s10953-011-9678-2
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Densities of the binary mixture of nonane with decane were measured at temperatures from 283.15 to 353.15 K at atmospheric pressure (0.7 atm). Measurements have been made over the full range of compositions and for the pure compounds by using a vibrating-tube densimeter (VTD). Excess molar volumes have been obtained from these experimental results and were fitted to a Redlich-Kister type expansion. The excess molar volumes exhibit small positive and small negative deviations from ideal behavior in the temperature interval studied. Partial molar volumes and partial molar volumes at infinite dilution have been determined for each component.
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页码:621 / 631
页数:11
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