Crystal structure of anhydrous bismuth iodate, Bi(IO3)3

被引：37

作者：

Bentria, B

Benbertal, D

Bagieu-Beucher, M

Masse, R

Mosset, A

机构：

[1] Univ Grenoble 1, CNRS, Lab Cristallog, F-38042 Grenoble 9, France

[2] Univ Laghouat, Lab Sci Fondamentales, Laghouat, Algeria

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2003年 / 33卷 / 11期

关键词：

bismuth; iodate; structure; lanthanide iodates;

D O I：

10.1023/A:1027409929990

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Bismuth iodate was synthesized by precipitation from bismuth nitrate and iodic acid. The powder was dissolved in dilute nitric acid and single crystals were obtained by slow evaporation at 70degreesC. Bi(IO3)(3) crystallizes in the monoclinic system, space group P2(1)/n (Ndegrees 14), a = 8.8882(2) Angstrom, b = 5.9445(2) Angstrom, c = 15.2445(5) Angstrom, beta = 97.064(1) Angstrom. BiO9 polyhedra are edge-connected forming chains parallel to the b axis; these chains are linked through (IO3) groups forming layers parallel to (101). The 3D framework is designed by linking these layers through long I - O bonds. DSC analysis shows a remarkable thermal stability.

引用

页码：867 / 873

页数：7

共 22 条

[1] TRANSITION-METAL IODATES .7. CRYSTALLOGRAPHIC AND NONLINEAR OPTIC SURVEY OF 4F-IODATES
ABRAHAMS, SC
BERNSTEIN, JL
NASSAU, K
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1976, 16 (1-2) : 173 - 184
[2] ALTOMARE A, 1993, J APPL CRYSTALLOGR, V343, P26
[3] CRYSTAL STRUCTURES OF BI2O2SO4 . H2O AND BIOHSEO4 . H2O
AURIVILLIUS, B
[J]. ACTA CHEMICA SCANDINAVICA, 1964, 18 (10): : 2375 - +
[4] CRYSTAL STRUCTURE OF ORTHORHOMBIC MODIFICATION OF BIOHCRO4 . A REFINEMENT OF STRUCTURE OF MONOCLINIC BIOHCRO4
AURIVILLIUS, B
LOWENHIE.A
[J]. ACTA CHEMICA SCANDINAVICA, 1964, 18 (08): : 1937 - +
[5] AURIVILLIUS B, 1962, ARK KEMI, V19, P271
[6] Crystal engineering strategy for quadratic nonlinear optics.: Part II:: Hg(IO3)2
Bentria, B
Benbertal, D
Bagieu-Beucher, M
Mosset, A
Zaccaro, J
[J]. SOLID STATE SCIENCES, 2003, 5 (02) : 359 - 365
[7] NEW NONLINEAR OPTICAL MATERIALS - METAL OXIDES WITH NONBONDED ELECTRONS
BERGMAN, JG
BOYD, GD
ASHKIN, A
[J]. JOURNAL OF APPLIED PHYSICS, 1969, 40 (07) : 2860 - +
[8] AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY
BLESSING, RH
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 : 33 - 38
[9] Tetra(4-methoxyphenyl)phosphonium iodide: A twinned crystal built up with three-dimensional octupolar nonlinear optical chromophores
Bourgogne, C
Le Fur, Y
Juen, P
Masson, P
Nicoud, JF
Masse, R
[J]. CHEMISTRY OF MATERIALS, 2000, 12 (04) : 1025 - 1033
[10] BOND-VALENCE PARAMETERS FOR SOLIDS
BRESE, NE
OKEEFFE, M
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 : 192 - 197

← 1 2 3 →