Crystallization of Y3Al5O12:Ce3+ glass microspheres prepared by flame-spraying synthesis

被引:5
作者
He, Gang [1 ,2 ]
Liu, Guanghua [1 ]
Guo, Shibin [1 ]
Yang, Zengchao [1 ]
Li, Jiangtao [1 ]
机构
[1] Chinese Acad Sci, Tech Inst Phys & Chem, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
基金
北京市自然科学基金; 中国国家自然科学基金;
关键词
MOLTEN-SALT SYNTHESIS; LUMINESCENCE PROPERTIES; PHOSPHORS; ALUMINA;
D O I
10.1007/s10854-014-2365-5
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Ce3+-doped Y3Al5O12 microspheres and microcubes were prepared by controlled crystallization of flame-sprayed glass microspheres. The morphology and microstructure of the Y3Al5O12:Ce3+ phosphor particles were affected by the heat-treatment temperature and the crystallization environment. Powder sample heat-treated in air was composed of randomly aggregated grains and their size can be tuned from nanometer scale to micrometer size by adjusting the heat-treatment temperature. Cubic Y3Al5O12:Ce3+ particles were obtained when the glass microspheres were heat-treated in NaCl-NaF molten salt medium. The formation mechanisms for the Y3Al5O12:Ce3+ microspheres and microcubes were analyzed. The photoluminescence spectra of the prepared Y3Al5O12:Ce3+ microspheres and microcubes were investigated.
引用
收藏
页码:72 / 77
页数:6
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