Development and characterization of novel hydrophilic surface modifying macromolecule for polymeric membranes

被引:119
作者
Rana, D
Matsuura, T
Narbaitz, RM
Feng, C
机构
[1] Univ Ottawa, Dept Chem Engn, Ind Membrane Res Inst, Ottawa, ON K1N 6N5, Canada
[2] Univ Ottawa, Dept Civil Engn, Ind Membrane Res Inst, Ottawa, ON K1N 6N5, Canada
关键词
hydrophilic surface modifying macromolecule; polyethersulfone; contact angle; ultra-filtration; fouling resistance;
D O I
10.1016/j.memsci.2004.09.034
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A hydrophilic Surface Modifying Macromolecule (LSMM) was synthesized, characterized, and blended into the casting solution of polyethersulfone (PES) membranes. Ultra-filtration membranes were prepared by the phase inversion technique. The membranes were then characterized by contact angle measurements and a solute transport study using poly(ethylene glycol) (PEG) and poly(ethylene oxide) (PEO) solutes of different molecular weights. Pore size and pore size distribution of the membranes were determined by using PEG and PEO separation data. The Ottawa River water was treated by the membranes. The LSMM blended PES membranes showed higher fouling resistance and long-term stability than the PES membrane without LSMM. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:103 / 112
页数:10
相关论文
共 34 条
[1]   PREFERENTIAL SURFACE-ADSORPTION IN MISCIBLE BLENDS OF POLYSTYRENE AND POLYVINYL METHYL-ETHER) [J].
BHATIA, QS ;
PAN, DH ;
KOBERSTEIN, JT .
MACROMOLECULES, 1988, 21 (07) :2166-2175
[2]   POLYSULFONE HOLLOW FIBERS .1. SPINNING AND PROPERTIES [J].
CABASSO, I ;
KLEIN, E ;
SMITH, JK .
JOURNAL OF APPLIED POLYMER SCIENCE, 1976, 20 (09) :2377-2394
[3]   Surface enrichment in polymer blends involving hydrogen bonding [J].
Duan, YZ ;
Pearce, EM ;
Kwei, TK ;
Hu, XS ;
Rafailovich, M ;
Sokolov, J ;
Zhou, KG ;
Schwarz, S .
MACROMOLECULES, 2001, 34 (19) :6761-6767
[4]   Transformation of a simple plastic into a superhydrophobic surface [J].
Erbil, HY ;
Demirel, AL ;
Avci, Y ;
Mert, O .
SCIENCE, 2003, 299 (5611) :1377-1380
[5]   EFFECT OF SURFACE-MODIFYING MACROMOLECULES AND SOLVENT EVAPORATION TIME ON THE PERFORMANCE OF POLYETHERSULFONE MEMBRANES FOR THE SEPARATION OF CHLOROFORM WATER MIXTURES BY PERVAPORATION [J].
FANG, Y ;
PHAM, VA ;
MATSUURA, T ;
SANTERRE, JP ;
NARBAITZ, RM .
JOURNAL OF APPLIED POLYMER SCIENCE, 1994, 54 (12) :1937-1943
[6]   Development of membranes with low surface energy to reduce the fouling in ultrafiltration applications [J].
Hamza, A ;
Pham, VA ;
Matsuura, T ;
Santerre, JP .
JOURNAL OF MEMBRANE SCIENCE, 1997, 131 (1-2) :217-227
[7]  
HER N, 2003, MEMBR TECHN C P AM W
[8]   Design and performance of foul-resistant poly(vinylidene fluoride) membranes prepared in a single-step by surface segregation [J].
Hester, JF ;
Mayes, AM .
JOURNAL OF MEMBRANE SCIENCE, 2002, 202 (1-2) :119-135
[9]  
Ho JY, 2000, J BIOMAT SCI-POLYM E, V11, P1085
[10]   pH-sensitive gating by conformational change of a polypeptide brush grafted onto a porous polymer membrane [J].
Ito, Y ;
Ochiai, Y ;
Park, YS ;
Imanishi, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (07) :1619-1623