Solid imidazolium halide catalysts for the solvent free synthesis of glycerol carbonate

被引：4

作者：

Appaturi, Jimmy Nelson ^{[1
]}

Ng, Eng-Poh ^{[1
]}

Adam, Farook ^{[1
]}

机构：

[1] Univ Sains Malaysia, Sch Chem Sci, George Town 11800, Malaysia

来源：

JOURNAL OF CO2 UTILIZATION | 2014年 / 6卷

关键词：

MCM-41; Cycloaddition; Carbon dioxide; Glycerol carbonate; Glycidol; STYRENE OXIDE; EFFICIENT SYNTHESIS; CYCLIC CARBONATES; SUPERCRITICAL CO2; EPOXIDES; DIOXIDE; GLYCIDOL; FACILE;

D O I：

10.1016/j.jcou.2014.01.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of glycidol carbonate via the cycloaddition of carbon dioxide and glycidol had been studied using MCM-41-Imi/x (x = Cl, Br and I) catalysts under solvent free condition. Within the limit of experimental error, all three catalysts showed a yield > 97.2% at 90 degrees C, 20 bar CO2 pressure and a reaction time of 4 h. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：69 / 74

页数：6

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