A comparative study of the reactions of fluorinated oxi- and thiiranes with acyl chlorides

被引：0
|
作者：
Nalet'ko, S. A. [1 ]
Pervova, M. G. [1 ]
Kodess, M. I. [1 ]
Toporova, M. S. [1 ]
Gorbunova, T. I. [1 ]
Zapevalov, A. Ya. [1 ]
Saloutin, V. I. [1 ]
机构：
[1] Russian Acad Sci, Ural Branch, I Ya Postovsky Inst Organ Synth, 22-20 Ul S Kovalevskoy Akad Skaya, Ekaterinburg 620990, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2017年 / 66卷 / 06期
关键词：
fluorinated oxi- and thiiranes; acyl chlorides; regioisomers; ETHERS; ALCOHOLS;
D O I：
10.1007/s11172-017-1848-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The CoCl2-catalyzed reactions of fluorinated 1,2-oxi- and thiiranes with acyl chlorides were studied. It was found that a regioselective heterocycle opening reaction resulted in two isomers having normal and abnormal structure in a ratio predetermined by the substituents in both the starting heterocycles and acyl chlorides.
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收藏
页码：1011 / 1017
页数：7
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