Effect of a constant magnet position and intensity on a copper layer obtained by DC electrodeposition

被引:1
作者
Susetyo, F. B. [1 ,2 ]
Soegijono, B. [1 ]
Yusmaniar [3 ]
机构
[1] Univ Indonesia, Dept Phys, Depok 16424, Indonesia
[2] Univ Negeri Jakarta, Dept Mech Engn, Jakarta 13220, Indonesia
[3] Univ Negeri Jakarta, Dept Chem, Jakarta 13220, Indonesia
来源
INTERNATIONAL JOURNAL OF CORROSION AND SCALE INHIBITION | 2021年 / 10卷 / 02期
关键词
magnet; position; electrodeposition; copper; Al alloy; GRAIN-SIZE; FIELD; MICROSTRUCTURE; HARDNESS; DEPOSITION; BEHAVIOR; CU; METALLIZATION; SURFACE;
D O I
10.17675/2305-6894-2021-10-2-18
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Copper (Cu) has high electrical and thermal conductivity compared with aluminium (Al); therefore, Cu has replaced Al as a metal for interconnects. In particular, Al coated with Cu will provide the benefit of reducing production costs. In this work, the Cu layer was fabricated using an electrodeposition process under the influence of a constant magnetic field. A single constant magnet field is placed perpendicular with a substrate using various magnetic intensities and positioning of the magnetic pole. The cathodic current efficiency, deposition rate, surface morphology, oxygen content, crystallographic orientation, corrosion rate, corrosion potential, and microhardness were measured and analyzed. The results show that by exerting a constant magnet during electrodeposition, the cathodic current efficiency, deposition rate, peak (111) intensities, and hardness of the Cu layer significant increase. The crystal systems of all the Cu layer is a cubic structure (FCC) with FM-3M space group, and three significant peaks are seen based on high score refinement. Three significant peaks are seen in (111), (002), and (022) planes with various preferred orientations. The preferred orientation shifted from (022) to (111) plane when a constant magnet was applied. Furthermore, the Cu 1-14N sample displays better hardness and corrosion resistance with values of 255.2 HV and 0.023 mmpy, respectively.
引用
收藏
页码:766 / 782
页数:17
相关论文
共 37 条
  • [11] Alginate biopolymer as green corrosion inhibitor for copper in 1 M hydrochloric acid: Experimental and theoretical approaches
    Jmiai, A.
    El Ibrahimi, B.
    Tara, A.
    El Issami, S.
    Jbara, O.
    Bazzi, L.
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2018, 1157 : 408 - 417
  • [12] Copper Thin Film Deposited By PVD on Aluminum AA4015 Substrate for Thermal Solar Application
    Kadhim, Mohammed J.
    Sukkar, Khalid A.
    Abbas, Ahmed S.
    [J]. 2ND INTERNATIONAL CONFERENCE ON SUSTAINABLE ENGINEERING TECHNIQUES (ICSET 2019), 2019, 518
  • [13] Properties of copper films prepared by chemical vapor deposition for advanced metallization of microelectronic devices
    Kröger, R
    Eizenberg, M
    Cong, D
    Yoshida, N
    Chen, LY
    Ramaswami, S
    Carl, D
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (09) : 3248 - 3254
  • [14] Change of hardness of copper sheet by spliting process
    Kurumada, Akira
    Itoh, Goroh
    Sugita, Masamichi
    Sakuma, Takaaki
    Seki, Masakatsu
    [J]. 11TH INTERNATIONAL CONFERENCE ON TECHNOLOGY OF PLASTICITY, ICTP 2014, 2014, 81 : 861 - 866
  • [15] Mechanical properties and optimal grain size distribution profile of gradient grained nickel
    Lin, Y.
    Pan, J.
    Zhou, H. F.
    Gao, H. J.
    Li, Y.
    [J]. ACTA MATERIALIA, 2018, 153 : 279 - 289
  • [16] Evaluation of K3Fe(CN)6 on Deposition Behavior and Structure of Electroless Copper Plating
    Lu, Jianhong
    Wang, Mingyong
    Deng, Xiaomei
    Yan, Jianhei
    Yun, Jimmy
    Jiao, Shuqiang
    [J]. ELECTROCHEMISTRY, 2019, 87 (04) : 214 - 219
  • [17] Comparative study of the copper inhibition of two [H4L]calixarenic molecules in sulfuric acid medium
    M'hanni, N.
    Galai, M.
    Ouakki, M.
    Touhami, M. Ebn
    Rifi, E. H.
    Asfari, Z.
    [J]. INTERNATIONAL JOURNAL OF CORROSION AND SCALE INHIBITION, 2020, 9 (03): : 1037 - 1048
  • [18] Effects of magnetic fields on iron electrodeposition
    Matsushima, H
    Nohira, T
    Mogi, I
    Ito, Y
    [J]. SURFACE & COATINGS TECHNOLOGY, 2004, 179 (2-3) : 245 - 251
  • [19] Effect of applied magnetic field on microstructure of electrodeposited copper
    Murdoch, Heather A.
    Yin, Denise
    Hernandez-Rivera, Efrain
    Giri, Anit K.
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2018, 97 : 11 - 15
  • [20] Microstructure in copper interconnects - Influence of plating additive concentration
    Neuner, Juergen
    Zienert, Inka
    Peeva, Anita
    Preusse, Axel
    Kuecher, Peter
    Bartha, Johann W.
    [J]. MICROELECTRONIC ENGINEERING, 2010, 87 (03) : 254 - 257