Preparation, electrical conductivity and magnetic susceptibility of Eu2Mn2/3Nb4/3O7

被引：11
|
作者：
Chen, G
Takenoshita, H
Kamegashira, N
机构：
[1] Department of Materials Science, Toyohashi University of Technology, Toyohashi, 441, Tempaku-cho
来源：
MATERIALS LETTERS | 1996年 / 27卷 / 06期
关键词：
complex oxides; electrical conductivity; magnetic susceptibility; Eu2Mn2/3Nb4/3O7;
D O I：
10.1016/0167-577X(96)00003-1
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new complex oxide Eu2Mn2/3Nb4/3O7 with a pyrochlore-related structure has been prepared from Eu2O3, MnO and Nb2O5 at 1523 K in a reducing atmosphere. The X-ray diffraction patterns of this compound can be indexed by hexagonal symmetry with the lattice parameters a = 15.102(3) Angstrom, c=17.417(6) Angstrom. Electrical conductivity shows a semiconducting property. It is shown from the results of magnetic susceptibility that this compound has a paramagnetic property in the temperature range 77-600 K and that the valence numbers of Eu, Mn and Nb in Eu2Mn2/3Nb4/3O7 are 3(+), 2(+) and 5(+), respectively.
引用
收藏
页码：323 / 325
页数：3
相关论文
共 50 条
  • [31] Electrical conductivity of (Ni,Mn,Fe,Cu)3O4 ceramic semiconductors designed for temperature and magnetic field sensing
    Kubisztal, Marian
    Karolus, Malgorzata
    CERAMICS INTERNATIONAL, 2023, 49 (24) : 40268 - 40274
  • [32] Electrical conductivity of Li2O : B2O3 : ZnO glasses
    Gedam, RS
    Deshpande, AV
    Deshpande, VK
    INDIAN JOURNAL OF PHYSICS AND PROCEEDINGS OF THE INDIAN ASSOCIATION FOR THE CULTIVATION OF SCIENCE, 2005, 79 (07): : 741 - 743
  • [33] Crystal structure, conductivity, and magnetic susceptibility of Er2Te3
    Stowe, K
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (05): : 872 - 876
  • [34] Field-Assisted Sintering of Nb-Al2O3 Composite Materials and Investigation of Electrical Conductivity
    Kraft, Bastian
    Wagner, Susanne
    Schell, Karl G.
    Hoffmann, Michael J.
    ADVANCED ENGINEERING MATERIALS, 2022, 24 (08)
  • [35] Dependence of Ti2O3 and Temperature on Electrical Conductivity of TiO2-FeO-Ti2O3 Slags
    Li, Shengping
    Lv, Xuewei
    Fan, Gangqiang
    Lv, Wei
    Zhang, Yingyi
    APPLICATIONS OF PROCESS ENGINEERING PRINCIPLES IN MATERIALS PROCESSING, ENERGY AND ENVIRONMENTAL TECHNOLOGIES, 2017, : 335 - 341
  • [36] Electrical conductivity of NaF-AlF3-CaF2-Al2O3-ZrO2 molten salts
    Bao, Morigengaowa
    Wang, Zhao-wen
    Gao, Bing-liang
    Shi, Zhong-ning
    Hu, Xian-wei
    Yu, Jiang-yu
    TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2013, 23 (12) : 3788 - 3792
  • [37] Preparation, infrared and magnetic susceptibility studies of LnB3O6 (Ln = Gd, Eu and Sm)
    Rao, KK
    Vithal, M
    Ravinder, D
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2002, 253 (1-2) : 65 - 71
  • [38] Electrical Conductivity of the GdCl3–KCl–Gd2O3 Systems
    E. V. Nikolaeva
    I. D. Zakir’yanova
    A. L. Bovet
    T. V. Sosnovtseva
    Russian Metallurgy (Metally), 2020, 2020 : 817 - 820
  • [39] ELECTRICAL-CONDUCTIVITY OF V2O5-BI2O3-TEO2 GLASSES
    MORI, H
    KITAMI, T
    SAKATA, H
    NIPPON SERAMIKKUSU KYOKAI GAKUJUTSU RONBUNSHI-JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1993, 101 (03): : 347 - 353
  • [40] Correlation Between Electrical Conductivity and Catalytic Property in 78V2O5-15P2O5-7B2O3 Glass Containing Fe2O3
    Jeong, Hwa-Jin
    Kim, Jong-hwan
    Ryu, Bong-Ki
    KOREAN JOURNAL OF METALS AND MATERIALS, 2016, 54 (12): : 931 - 936
12345