6,6′-Di-(2"-thiophenol)-2,2′-bipyridine

被引：0
|
作者：
Huang, Yan [1 ]
Tong, Lianpeng [1 ]
机构：
[1] Guangzhou Univ, Sch Chem & Chem Engn, Higher Educ Mega Ctr, 230 Wai Huan Xi Rd, Guangzhou 510006, Peoples R China
来源：
MOLBANK | 2022年 / 2022卷 / 02期
关键词：
thiophenol; bipyridine; tetradentate ligand; hydrogenase; transition metal; coordination; CRYSTAL-STRUCTURE; HYDROGEN;
D O I：
10.3390/M1355
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This short note describes the synthesis of compound 6,6'-di-(2"-thiophenol)-2,2'-bipyridine from its methyl phenyl sulfane precursor via deprotection of the methyl groups. The product as well as the intermediate in the synthetic route have been characterized by UV-Vis spectroscopy, H-1- and C-13-NMR spectroscopy, FT-IR spectroscopy, and HR-MS analysis. This work presents a rare example of tetradentate chelators that bears pyridyl backbones and thiophenol donors for the coordination with 3d-transition metal cations.
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页数：5
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