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The Preparation and Photoluminescence Properties of Fluorosilicate Glass Ceramics Containing CeF3:Dy3+ Nanocrystals
被引:6
|作者:
Wu Li-Ang
[1
]
Fu Heng-Yi
[1
]
Qian Jiang-Yun
[1
]
Zhao Da-Liang
[1
]
Luo Qun
[1
]
Qiao Xu-Sheng
[1
]
Fan Xian-Ping
[1
]
Zhang Xiang-Hua
[2
]
机构:
[1] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
[2] Univ Rennes 1, Inst Chim Rennes, UMR CNRS Verres & Ceram 6512, F-35042 Rennes, France
基金:
中国国家自然科学基金;
关键词:
ENERGY-TRANSFER;
LUMINESCENCE;
ER3+;
MICROSTRUCTURE;
FUTURE;
UV;
D O I:
10.1088/0256-307X/29/1/017802
中图分类号:
O4 [物理学];
学科分类号:
0702 ;
摘要:
Ce3+ and Dy3+ co-doped oxyfluoride glasses and glass ceramics containing CeF3 nanocrystals are prepared in a reducing atmosphere. XRD measurements and the calculated lattice parameters suggest that Dy3+ ions are incorporated with precipitated CeF3 nanocrystals along with a rise in the Dy3+ concentration or an increase in the annealing temperature. The glass ceramics emit white light close to the CIE coordinates of (0.3,0.3), derived from a combination of Ce3+ and Dy3+ emission. The CIE chromaticity coordinates of the Ce3+ and Dy3+ co-doped glass ceramics can be tuned by varying the ratio of Ce3+/Dy3+, while the luminescence intensity can be enhanced by heat treatment above 620 degrees C.
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页数:4
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