Direct in-situ modification of PVDF membranes with a zwitterionic copolymer to form bi-continuous and fouling resistant membranes

被引:73
作者
Dizon, Gian Vincent
Venault, Antoine [1 ]
机构
[1] Chung Yuan Christian Univ, R&D Ctr Membrane Technol, Chungli 32023, Taiwan
关键词
PVDF membrane; PS-r-PEGMA-r-PSBMA copolymer; VIPS process; Membrane formation; Biofouling; POLY(VINYLIDENE FLUORIDE) MEMBRANES; IMPROVED ANTIFOULING PROPERTIES; ULTRAFILTRATION MEMBRANES; SURFACE-PROPERTIES; POLY(ETHYLENE GLYCOL); POLYETHYLENE-GLYCOL; PERFORMANCE; HEMOCOMPATIBILITY; FABRICATION; PROPERTY;
D O I
10.1016/j.memsci.2017.12.065
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This study addresses the challenge of blending poly(vinylidene fluoride) (PVDF) and a zwitterionic copolymer of styrene units, sulfobetaine methacrylate units and ethylene glycol methacrylate units (PS-r-PEGMA-r-PSBMA) to form fouling-resistant membranes in one step. Membranes with a lacy structure were obtained. Fouling tests highlighted the very good efficiency of the copolymer, but the influence of the zwitterionic groups was only seen in harsher conditions: the addition of PSBMA in the copolymer improved the fouling resistance after incubation of the membranes with fibrinogen from platelet-poor-plasma, bacteria or whole blood. The zwitterionic membrane outperformed the commercial hydrophilic PVDF membrane in permeability tests after incubation with a platelet-poor-plasma solution with a FRR of 91% while it was 66% with the commercial membrane. Overall, these results show that using a solubility enhancing block (here PEGMA) can permit to take full advantage of the excellent antifouling properties of zwitterionic materials and readily prepare fouling-resistant membranes in one step.
引用
收藏
页码:45 / 58
页数:14
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