[Zn2(BTDA)(bpy)(H2O)]•0.5bpy:: a new three-dimensional metal-organic framework constructed from flexible and rigid mixed ligands

被引：11

作者：

Hong, J ^{[1
]}

机构：

[1] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2005年 / 752卷 / 1-3期

关键词：

hydrothermal synthesis; crystal structure; mixed ligands; channel; luminescence;

D O I：

10.1016/j.molstruc.2005.06.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new three-dimensional metal-organic framework, [Zn2(BTDA)(bpy) (H2O)]·0.5bpy (1) (BTDC=3,3′,4,4′-benzophenone tetracarboxylate, bpy=4,4′-bipyridine), has been prepared with the contemporary use of two different kinds of ligands, the rigid 4,4′-bipyridyl (bpy) and the V-shaped flexible multi-carboxylic ligands H4BTDC, and characterized by single-crystal X-ray diffraction analysis. The three-dimensional framework is assembled from bpy-pillared two-dimensional sheets and contains one-dimensional rhombus channels with the dimensions of 4.06×12.07 Å. Furthermore, compound 1 shows blue photoluminescent property at room temperature. © 2005 Elsevier B.V. All rights reserved.

引用

页码：166 / 169

页数：4

共 23 条

[1]

Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO

[2]

2-Y

[3] Inorganic crystal engineering using self-assembly of tailored building-blocks [J].

Blake, AJ ;

Champness, NR ;

Hubberstey, P ;

Li, WS ;

Withersby, MA ;

Schröder, M .

COORDINATION CHEMISTRY REVIEWS, 1999, 183 :117-138

[4] A neutral 3D copper coordination polymer showing 1D open channels and the first interpenetrating NbO-type network [J].

Bu, XH ;

Tong, ML ;

Chang, HC ;

Kitagawa, S ;

Batten, SR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (02) :192-195

[5] Photoluminescence properties of multinuclear copper(I) compounds [J].

Ford, PC ;

Cariati, E ;

Bourassa, J .

CHEMICAL REVIEWS, 1999, 99 (12) :3625-3647

[6] Three novel polymeric frameworks assembled from CdII, CoII, and MnII with the mixed organic ligands 3,4-pyridinedicarboxylate, 1,3-bis(4-pyridyl)propane, or 1,2-bis(4-pyridyl)ethane [J].

Fu, ZY ;

Hu, SM ;

Dai, JC ;

Zhang, JJ ;

Wu, XT .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (14) :2670-2677

[7] Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type [J].

Galet, A ;

Niel, V ;

Muñoz, MC ;

Real, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (47) :14224-14225

[8]

Hagrman PJ, 1999, ANGEW CHEM INT EDIT, V38, P2639

[9] High-dimensional manganese(II) compounds with noncovalent and/or covalent bonds derived from flexible ligands: Self-assembly and structural transformation [J].

Hong, CS ;

Son, SK ;

Lee, YS ;

Jun, MJ ;

Do, YK .

INORGANIC CHEMISTRY, 1999, 38 (24) :5602-5610

[10] Functional porous coordination polymers [J].

Kitagawa, S ;

Kitaura, R ;

Noro, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (18) :2334-2375

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