Facile synthesis of amorphous UiO-66 (Zr-MOF) for supercapacitor application

被引：140
作者：
Yang, Fan [1 ]
Li, Weiyang [1 ]
Tang, Bohejin [1 ]
机构：
[1] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2018年 / 733卷
基金：
中国国家自然科学基金;
关键词：
Amorphous UiO-66; Zr-MOF; Supercapacitor; METAL-ORGANIC-FRAMEWORKS; HIGH-PERFORMANCE SUPERCAPACITOR; INDUCED AMORPHIZATION; ELECTRODE; LIQUIDS; FILM; TRANSITION; STABILITY; HYDROGEN; MNO2;
D O I：
10.1016/j.jallcom.2017.10.129
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An amorphous metal-organic framework (aMOF) UiO-66 (Zr-MOF) was prepared directly from synthesis, different from experiments involving heating, pressure, and ball-milling by other researchers. The as-prepared amorphous UiO-66 has been successfully used as a supercapacitor electrode material, exhibiting a high specific capacitance (920 F g(-1) at 10 mV s(-1)) superior to crystalline UiO-66. It has been verified that the material after reaction can still remain amorphous state by transmission electron microscopy (TEM). The capacitance of amorphous UiO-66 can maintain 610 F g(-1) after 5000 cycles, suggesting its promising potential as a supercapacitor electrode material. (C) 2017 Elsevier B.V. All rights reserved.
引用
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页码：8 / 14
页数：7
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共 43 条
  • [1] Nanosize Zr-metal organic framework (UiO-66) for hydrogen and carbon dioxide storage
    Abid, Hussein Rasool
    Tian, Huyong
    Ang, Ha-Ming
    Tade, Moses O.
    Buckley, Craig E.
    Wang, Shaobin
    [J]. CHEMICAL ENGINEERING JOURNAL, 2012, 187 : 415 - 420
  • [2] Synthesis, characterization, and electrochemical properties of ultrafine β-Ni(OH)2 nanoparticles
    Aghazadeh, Mustafa
    Golikand, Ahmad Nozad
    Ghaemi, Mehdi
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (14) : 8674 - 8679
  • [3] Carbons and Electrolytes for Advanced Supercapacitors
    Beguin, Francois
    Presser, Volker
    Balducci, Andrea
    Frackowiak, Elzbieta
    [J]. ADVANCED MATERIALS, 2014, 26 (14) : 2219 - 2251
  • [4] Metal Organic Framework-Derived Metal Phosphates as Electrode Materials for Supercapacitors
    Bendi, Ramaraju
    Kumar, Vipin
    Bhavanasi, Venkateswarlu
    Parida, Kaushik
    Lee, Pooi See
    [J]. ADVANCED ENERGY MATERIALS, 2016, 6 (03)
  • [5] DYNAMICS OF SUPERCOOLED LIQUIDS AND THE GLASS-TRANSITION
    BENGTZELIUS, U
    GOTZE, W
    SJOLANDER, A
    [J]. JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1984, 17 (33): : 5915 - 5934
  • [6] Amorphous Metal-Organic Frameworks
    Bennett, Thomas D.
    Cheetham, Anthony K.
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (05) : 1555 - 1562
  • [7] Ball-Milling-Induced Amorphization of Zeolitic Imidazolate Frameworks (ZIFs) for the Irreversible Trapping of Iodine
    Bennett, Thomas D.
    Saines, Paul J.
    Keen, David A.
    Tan, Jin-Chong
    Cheetham, Anthony K.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (22) : 7049 - 7055
  • [8] Reversible pressure-induced amorphization of a zeolitic imidazolate framework (ZIF-4)
    Bennett, Thomas D.
    Simoncic, Petra
    Moggach, Stephen A.
    Gozzo, Fabia
    Macchi, Piero
    Keen, David A.
    Tan, Jin-Chong
    Cheetham, Anthony K.
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (28) : 7983 - 7985
  • [9] Crystalline MnO2 as possible alternatives to amorphous compounds in electrochemical supercapacitors
    Brousse, Thierry
    Toupin, Mathieu
    Dugas, Romain
    Athouel, Laurence
    Crosnier, Olivier
    Belanger, Daniel
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2006, 153 (12) : A2171 - A2180
  • [10] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability
    Cavka, Jasmina Hafizovic
    Jakobsen, Soren
    Olsbye, Unni
    Guillou, Nathalie
    Lamberti, Carlo
    Bordiga, Silvia
    Lillerud, Karl Petter
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) : 13850 - 13851
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