Highly Catalytic Performance of La2O3 in the Selective Transfer Hydrogenation of Biomass-derived Furfural

被引：11

作者：

Natsir, Taufik Abdillah ^{[1
,2
]}

Hara, Takayoshi ^{[1
]}

Ichikuni, Nobuyuki ^{[1
]}

Shimazu, Shogo ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Engn, Inage Ku, 1-33 Yayoi, Chiba 2638522, Japan

[2] Univ Gadjah Mada, Dept Chem, Sekip Utara Bulaksumur 55281, Yogyakarta, Indonesia

来源：

CHEMISTRY LETTERS | 2017年 / 46卷 / 10期

关键词：

Furfural; Transfer hydrogenation; La2O3;

D O I：

10.1246/cl.170720

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly catalytic performance of La2O3 in transfer hydrogenation reactions was achieved following pretreatment involving a sequence of heat treatments under different atmospheric gases. Furfural (FFR) was converted to furfuryl alcohol (FFA) in a very selective manner (98% conversion, with 96% selectivity) using La2O3 that had been calcined under air at 923K and treated under H-2 at 673 K. Strongly basic sites and weakly acidic sites were generated after heat pretreatment.

引用

页码：1580 / 1583

页数：4

共 36 条

[1] Single Pot Transfer Hydrogenation and Aldolization of Furfural Over Metal Oxide Catalysts [J].

Biradar, N. S. ;

Hengne, A. M. ;

Sakate, S. S. ;

Swami, R. K. ;

Rode, C. V. .

CATALYSIS LETTERS, 2016, 146 (08) :1611-1619

[2] Acid-catalyzed polycondensation of furfuryl alcohol: Mechanisms of chromophore formation and cross-linking [J].

Choura, M ;

Belgacem, NM ;

Gandini, A .

MACROMOLECULES, 1996, 29 (11) :3839-3850

[3] AN XPS STUDY OF METAL SUPPORT INTERACTIONS ON PD/SIO2 AND PD/LA2O3 [J].

FLEISCH, TH ;

HICKS, RF ;

BELL, AT .

JOURNAL OF CATALYSIS, 1984, 87 (02) :398-413

[4] The Rapid Formation of La(OH)3 from La2O3 Powders on Exposureto Water Vapor [J].

Fleming, Peter ;

Farrell, Richard A. ;

Holmes, Justin D. ;

Morris, Michael A. .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2010, 93 (04) :1187-1194

[5] Combustion synthesized La2O3 and La(OH)3: recyclable catalytic activity towards Knoevenagel and Hantzsch reactions [J].

Gangwar, Bhanu P. ;

Palakollu, Veerabhadraiah ;

Singh, Archana ;

Kanvah, Sriram ;

Sharma, Sudhanshu .

RSC ADVANCES, 2014, 4 (98) :55407-55416

[6] Promotional Role of Surface Defects on Carbon-Supported Ruthenium-Based Catalysts in the Transfer Hydrogenation of Furfural [J].

Gao, Zhi ;

Yang, Lan ;

Fan, Guoli ;

Li, Feng .

CHEMCATCHEM, 2016, 8 (24) :3769-3779

[7] Acido-basicity of lanthana/alumina catalysts and their activity in ethanol conversion [J].

Garbarino, Gabriella ;

Wang, Chongyang ;

Valsamakis, Ioannis ;

Chitsazan, Sahar ;

Riani, Paola ;

Finocchio, Elisabetta ;

Flytzani-Stephanopoulos, Maria ;

Busca, Guido .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 200 :458-468

[8] Heterogeneous Catalytic Transfer Hydrogenation as an Effective Pathway in Biomass Upgrading [J].

Gilkey, Matthew J. ;

Xu, Bingjun .

ACS CATALYSIS, 2016, 6 (03) :1420-1436

[9] Chemoselective Hydrogenation of Biomass-Derived 5-Hydroxymethylfurfural into the Liquid Biofuel 2,5-Dimethylfuran [J].

Hu, Lei ;

Lin, Lu ;

Liu, Shijie .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (24) :9969-9978

[10] Synthesis of alumina-carbon composite material for the catalytic conversion of furfural to furfuryl alcohol [J].

Kim, Min Soo ;

Simanjuntak, Fidelis Stefanus Hubertson ;

Lim, Seoyeon ;

Jae, Jungho ;

Ha, Jeong-Myeong ;

Lee, Hyunjoo .

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2017, 52 :59-65

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