Influence of Inorganic Gases on Formation and Chemical Composition of Monoaromatic Hydrocarbons Secondary Organic Aerosol

被引：4
作者：
Xu, Jun [1 ]
Huang, Ming-Qiang [1 ]
机构：
[1] Minnan Normal Univ, Fujian Prov Key Lab Modern Analyt Sci & Separat T, Coll Chem & Chem Engn & Environm, Zhangzhou 363000, Peoples R China
来源：
CHINESE JOURNAL OF ANALYTICAL CHEMISTRY | 2020年 / 48卷 / 04期
基金：
中国国家自然科学基金;
关键词：
Inorganic gases; Monoaromatic hydrocarbons; Secondary organic aerosol; Chemical composition; Formation mechanism; Review; ATMOSPHERIC OXIDATION MECHANISM; BROWN CARBON CONSTITUENTS; FLIGHT MASS-SPECTROMETER; PARTICULATE PRODUCTS; INITIATED OXIDATION; REFRACTIVE-INDEXES; PARTICLE FORMATION; SIZE DISTRIBUTION; SEED AEROSOLS; ALPHA-PINENE;
D O I：
10.19756/j.issn.0253-3820.191235
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
SO2, NOx and NH3 are low molecular weight inorganic gas and are commonly found in the atmosphere that can affect the formation and chemical composition of secondary organic aerosols ( SOA ) through photochemical reaction processes. Volatile organic compounds ( VOCs ) from motor vehicle exhaust, such as monoaromatic hydrocarbons, are an important component of urban fine particulate matter, which has a significant impact on climate change, human health and atmospheric visibility. However, previous studies focused on photooxidation of biogenic volatile organic compounds, and relatively few on the reaction of anthropogenic monoaromatic hydrocarbons with high content in the atmosphere with inorganic gases such as SO2, NOx and NH3. This paper summarizes the photochemical mechanism and five kinds of common chemical composition of the laboratory simulation of OH radical to initiate monoaromatic hydrocarbons formation of SOA, and the effects of SO2, NOx and NH3 on the formation and chemical composition of monoaromatic hydrocarbons SOA by homogeneous and heterogeneous chemical reactions are also discussed. It is helpful to understand the formation mechanism and chemical composition of SOA and atmospheric brown carbon under the conditions of complex atmospheric pollution, and has certain reference significance for the prevention, control and treatment of air pollution in china at present.
引用
收藏
页码：449 / 462
页数：14
相关论文
共 100 条
[1]  
Babar Z.B., 2017, ATMOS ENVIRON, V164, P71, DOI DOI 10.1016/J.ATM0SENV.2017.05.034
[2]   Aerosols in Clearer Focus [J].
Baltensperger, Urs .
SCIENCE, 2010, 329 (5998) :1474-1475
[3]   Chemical characterization of organosulfates from the hydroxyl radical-initiated oxidation and ozonolysis of cis-3-hexen-1-ol [J].
Barbosa, Thais S. ;
Riva, Matthieu ;
Chen, Yuzhi ;
da Silva, Cleyton M. ;
Ameida, Jose Claudino S. ;
Zhang, Zhenfa ;
Gold, Avram ;
Arbilla, Graciela ;
Bauerfeldt, Glauco F. ;
Surratt, Jason D. .
ATMOSPHERIC ENVIRONMENT, 2017, 162 :141-151
[4]   Degradation of SO2, NO2 and NH3 leading to formation of secondary inorganic aerosols: An environmental chamber study [J].
Behera, Sailesh N. ;
Sharma, Mukesh .
ATMOSPHERIC ENVIRONMENT, 2011, 45 (24) :4015-4024
[5]   Uptake of gas-phase SO2, H2S, and CO2 by aqueous solutions [J].
Boniface, J ;
Shi, Q ;
Li, YQ ;
Cheung, JL ;
Rattigan, OV ;
Davidovits, P ;
Worsnop, DR ;
Jayne, JT ;
Kolb, CE .
JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (32) :7502-7510
[6]   Reactions of Methanesulfonic Acid with Amines and Ammonia as a Source of New Particles in Air [J].
Chen, Haihan ;
Varner, Mychel E. ;
Gerber, R. Benny ;
Finlayson-Pitts, Barbara J. .
JOURNAL OF PHYSICAL CHEMISTRY B, 2016, 120 (08) :1526-1536
[7]   Synergetic formation of secondary inorganic and organic aerosol: effect of SO2 and NH3 on particle formation and growth [J].
Chu, Biwu ;
Zhang, Xiao ;
Liu, Yongchun ;
He, Hong ;
Sun, Yele ;
Jiang, Jingkun ;
Li, Junhua ;
Hao, Jiming .
ATMOSPHERIC CHEMISTRY AND PHYSICS, 2016, 16 (22) :14219-14230
[8]   Secondary organic aerosol formation from photo-oxidation of toluene with NOx and SO2: Chamber simulation with purified air versus urban ambient air as matrix [J].
Deng, Wei ;
Liu, Tengyu ;
Zhang, Yanli ;
Situ, Shuping ;
Hu, Qihou ;
He, Quanfu ;
Zhang, Zhou ;
Lu, Sujun ;
Bi, Xinhui ;
Wang, Xuemei ;
Boreave, Antoinette ;
George, Christian ;
Ding, Xiang ;
Wang, Xinming .
ATMOSPHERIC ENVIRONMENT, 2017, 150 :67-76
[9]   Significant Increase of Aromatics-Derived Secondary Organic Aerosol during Fall to Winter in China [J].
Ding, Xiang ;
Zhang, Yu-Qing ;
He, Quan-Fu ;
Yu, Qing-Qing ;
Wang, Jun-Qi ;
Shen, Ru-Qin ;
Song, Wei ;
Wang, Yue-Si ;
Wang, Xin-Ming .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2017, 51 (13) :7432-7441
[10]   Impact of aerosol liquid water on secondary organic aerosol yields of irradiated toluene/propylene/NOx/(NH4)2 SO4/air mixtures [J].
Edney, EO ;
Driscoll, DJ ;
Speer, RE ;
Weathers, WS ;
Kleindienst, TE ;
Li, W ;
Smith, DF .
ATMOSPHERIC ENVIRONMENT, 2000, 34 (23) :3907-3919
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