Water Adsorption Characteristics of MIL-101 for Heat-Transformation Applications of MOFs

被引：296

作者：

Ehrenmann, Johannes ^{[1
,2
]}

Henninger, Stefan K. ^{[1
]}

Janiak, Christoph ^{[2
]}

机构：

[1] Fraunhofer Inst Solar Energy Syst ISE, Dept Thermal Syst & Bldg, D-79110 Freiburg, Germany

[2] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 04期

关键词：

Metal-organic frameworks; Mesoporous materials; Adsorption; Adsorption chilling; Heat transformation; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CATALYTIC-ACTIVITY; HYDROGEN STORAGE;

D O I：

10.1002/ejic.201001156

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The adsorption of water vapor in the highly porous metal-organic framework (MOF) of 3D-[Cr3F(H2O)(2)O(bdc)(3)center dot similar to 25H(2)O] (MIL-101) (bdc = benzene-1,4-dicarboxylate, terephthalate) of up to 1 g of water per gram of sorbent material (between 140 degrees C and 40 degrees C under a water vapor pressure of 5.6 kPa) together with the stability over several cycles makes MIL-101 the most promising material, so far, for heat transformation applications like thermally driven heat pumps or adsorption chillers.

引用

页码：471 / 474

页数：4

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