Hollow Nanostructures of Molybdenum Sulfides for Electrochemical Energy Storage and Conversion

被引：103
作者：
Yu, Xin-Yao [1 ]
Yu, Le [1 ]
Lou, Xiong Wen [1 ]
机构：
[1] Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore
来源：
SMALL METHODS | 2017年 / 1卷 / 1-2期
关键词：
ENHANCED ELECTROCATALYTIC ACTIVITY; ACTIVE EDGE SITES; LITHIUM STORAGE; MOS2; MICROSPHERES; FACILE SYNTHESIS; HYDROTHERMAL SYNTHESIS; TEMPLATE SYNTHESIS; EVOLUTION; CARBON; SPHERES;
D O I：
10.1002/smtd.201600020
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hollow nanostructures of molybdenum sulfides (MoSx, x = 2 or 3) hold great promise as electrode materials for various energy-related systems owing to their attractive electrochemical properties. Recent advances in the synthesis of hollow MoSx nanostructures with tailored morphology and composition are introduced, along with their applications in electrochemical energy storage and conversion, including lithium-ion batteries and the electrocatalytic hydrogen-evolution reaction. The importance of structural and compositional engineering on the electrochemical performance of hollow MoSx nanostructures is highlighted. Specifically, bare hollow MoSx structures, including hollow spheres and hollow polyhedral nanostructures, hollow MoSx-carbon composite structures, and hollow transition-metal-incorporated MoSx structures are discussed. Finally, a perspective is provided on current challenges and future research directions in this area.
引用
收藏
页数：8
相关论文
共 42 条
[1]   Graphene-like MoS2/amorphous carbon composites with high capacity and excellent stability as anode materials for lithium ion batteries [J].
Chang, Kun ;
Chen, Weixiang ;
Ma, Lin ;
Li, Hui ;
Li, He ;
Huang, Feihe ;
Xu, Zhude ;
Zhang, Qingbo ;
Lee, Jim-Yang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (17) :6251-6257
[2]   Hierarchical MoS2 tubular structures internally wired by carbon nanotubes as a highly stable anode material for lithium-ion batteries [J].
Chen, Yu Ming ;
Yu, Xin Yao ;
Li, Zhen ;
Paik, Ungyu ;
Lou, Xiong Wen .
SCIENCE ADVANCES, 2016, 2 (07)
[3]   Co-Doped MoS2 Nanosheets with the Dominant CoMoS Phase Coated on Carbon as an Excellent Electrocatalyst for Hydrogen Evolution [J].
Dai, Xiaoping ;
Du, Kangli ;
Li, Zhanzhao ;
Liu, Mengzhao ;
Ma, Yangde ;
Sun, Hui ;
Zhang, Xin ;
Yang, Ying .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (49) :27242-27253
[4]  
Dong B, 2016, INT J ELECTROCHEM SC, V11, P2846
[5]   Instant gelation synthesis of 3D porous MoS2@C nanocomposites for lithium ion batteries [J].
Fei, Ling ;
Xu, Yun ;
Wu, Xiaofei ;
Chen, Gen ;
Li, Yuling ;
Li, Binsong ;
Deng, Shuguang ;
Smirnov, Sergei ;
Fan, Hongyou ;
Luo, Hongmei .
NANOSCALE, 2014, 6 (07) :3664-3669
[6]   Three-dimensional nanotube electrode arrays for hierarchical tubular structured high-performance pseudocapacitors [J].
Gao, Yuan ;
Lin, Yuanjing ;
Chen, Jiaqi ;
Lin, Qingfeng ;
Wu, Yue ;
Su, Wenjun ;
Wang, Wenli ;
Fan, Zhiyong .
NANOSCALE, 2016, 8 (27) :13280-13287
[7]   Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction [J].
Geng, Xiumei ;
Sun, Weiwei ;
Wu, Wei ;
Chen, Benjamin ;
Al-Hilo, Alaa ;
Benamara, Mourad ;
Zhu, Hongli ;
Watanabe, Fumiya ;
Cui, Jingbiao ;
Chen, Tar-pin .
NATURE COMMUNICATIONS, 2016, 7
[8]   Hollow Structured Micro/Nano MoS2 Spheres for High Electrocatalytic Activity Hydrogen Evolution Reaction [J].
Guo, Bangjun ;
Yu, Ke ;
Li, Honglin ;
Song, Haili ;
Zhang, Yuanyuan ;
Lei, Xiang ;
Fu, Hao ;
Tan, Yinghua ;
Zhu, Zigiang .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (08) :5517-5525
[9]   Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts [J].
Jaramillo, Thomas F. ;
Jorgensen, Kristina P. ;
Bonde, Jacob ;
Nielsen, Jane H. ;
Horch, Sebastian ;
Chorkendorff, Ib .
SCIENCE, 2007, 317 (5834) :100-102
[10]   Template synthesis of hollow MoS2-carbon nanocomposites using microporous organic polymers and their lithium storage properties [J].
Jin, Jaewon ;
Kim, Bolyong ;
Kim, Mincheol ;
Park, Nojin ;
Kang, Sungah ;
Lee, Sang Moon ;
Kim, Hae Jin ;
Son, Seung Uk .
NANOSCALE, 2015, 7 (26) :11280-11285
12345