Synthesis of Diverse o-Arylthio-Substituted Diaryl Ethers by Direct Oxythiolation of Arynes with Diaryl Sulfoxides Involving Migratory O-Arylation

被引：48

作者：

Matsuzawa, Tsubasa ^{[1
]}

Uchida, Keisuke ^{[1
]}

Yoshida, Suguru ^{[1
]}

Hosoya, Takamitsu ^{[1
]}

机构：

[1] Tokyo Med & Dent Univ, Inst Biomat & Bioengn, Lab Chem Biosci, Chiyoda Ku, 2-3-10 Kanda Surugadai, Tokyo 1010062, Japan

来源：

ORGANIC LETTERS | 2017年 / 19卷 / 20期

关键词：

C-H ACTIVATION; BOND; PRECURSORS; GENERATION; BENZDIYNE; CHEMISTRY; INSERTION; REAGENTS; SULFIDES; IODIDES;

D O I：

10.1021/acs.orglett.7b02599

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A diverse range of o-arylthio-substituted diaryl ethers has been synthesized by direct oxythiolation of arynes with diaryl sulfoxides that involves the formation of the C-O and C-S bonds followed by migratory O-arylation.

引用

页码：5521 / 5524

页数：4

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