trans-Di-μ-chloro-bis[chloro(triphenylphosphine)palladium] benzene disolvate

被引：9
|
作者：
Sui-Seng, C [1 ]
Bélanger-Gariépy, F [1 ]
Zargarian, D [1 ]
机构：
[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷
关键词：
D O I：
10.1107/S1600536803015502
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, trans-[PdCl2(PPh3)](2), in the crystal structure of its benzene disolvate, [Pd2Cl4(C18H15P)(2)].-2C(6)H(6),occupies a special position in the inversion centre. The Pd atom has a distorted square-planar coordination environment formed by a triphenylphosphine [Pd-P 2.2278 (6) Angstrom], a terminal chloride [Pd-Cl 2.2722 (7) Angstrom], and two bridging chloride ligands. The Pd-mu-Cl bond in the transposition to the phosphine ligand [2.4128 (6) Angstrom] is considerably longer than the Pd-mu-Cl bond in the trans- position to the terminal chloride [2.3228 (6) Angstrom].
引用
收藏
页码：M618 / M619
页数：2
相关论文
共 50 条
  • [41] Di-μ-chloro-bis{chloro[hydrotris(pyrazol-1-yl)borato)](tetrahydrofuran) ytterbium(III)} toluene solvate
    Rabe, Gerd W.
    Zhang-Presse, Mei
    Riederer, Florian A.
    Rheingold, Arnold L.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M3149 - M3151
  • [42] Di-μ-chloro-bis{chloro[2-(4-methylphenylamino)-1,2-diphenylethanoximato]copper(II)}
    Puschmann, H
    Howard, JAK
    Soto, B
    Bonne, R
    Au-Alvarez, O
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : M581 - M583
  • [43] Bis[2-(3-pyridinio)benzimidazolium] di-μ-chloro-bis[trichlorocadmium(II)]
    Xia, CK
    Zhang, QZ
    Chen, SM
    He, X
    Lu, CZ
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2005, 61 : M203 - M205
  • [44] Bis[N-methylpiperidinium(2+)] di-μ-chloro-bis[tetrachlorobismuthate(III)] dihydrate
    Fu, YL
    Xu, ZW
    Ren, JL
    Ng, SW
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M1719 - M1720
  • [45] A novel trinuclear palladium cluster compound:: di-μ3-chloro-tris[chloro(triphenylphosphine-P)palladium] acetone solvate
    Sugimoto, K
    Kuroda-Sowa, T
    Yan, SG
    Maekawa, M
    Munakata, M
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2000, 56 : 414 - 415
  • [46] TEMPERATURE-VARIATION OF MECHANISM OF THERMAL-DECOMPOSITION OF DIOXYGENCARBONYL CHLORO-BIS (TRIPHENYLPHOSPHINE) IRIDIUM (I)
    BALL, MC
    THERMOCHIMICA ACTA, 1976, 14 (03) : 368 - 369
  • [47] The stereochemistry of chloro-bis(N-morpholino)phenylsilane
    Huber, G
    Schier, A
    Schmidbaur, H
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1999, 54 (01): : 18 - 20
  • [48] 1,4-Bis[chloro(hydroxyimino)methyl]benzene N,N′-dimethylformamide disolvate
    Liu, XG
    Feng, YQ
    Liu, DQ
    Zhao, Y
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O1970 - O1972
  • [49] Crystal　and　Molecular　Structure　of　Di－chloro－bis（р－methylphenylbutylsulfide） Palladium（Ⅱ）
    Guo Song-Shan
    Cui Li
    Wang Hang-Zhang
    Qian Pu(Department of Chemistry
    结构化学, 1994, (01) : 16 - 18
  • [50] KINETICS OF OXIDATIVE ADDITION OF HYDROGEN TO CHLORO(ACRYLONITRILE)-BIS(TRIPHENYLPHOSPHINE)RHODIUM(I) IN BENZENE
    OHTANI, Y
    YAMAGISHI, A
    FUJIMOTO, M
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1978, 51 (09) : 2562 - 2565
12345