Additive engineering induced perovskite crystal growth for high performance perovskite solar cells

被引:32
作者
Jin, Shao [1 ,3 ]
Wei, Yuelin [1 ,3 ]
Yang, Xiaomin [1 ,3 ]
Luo, Dan [1 ,3 ]
Fang, Yu [1 ,3 ]
Zhao, Yuezhu [1 ,3 ]
Guo, Qiyao [1 ,3 ]
Huang, Yunfang [2 ,3 ]
Fan, Leqing [1 ,3 ]
Wu, Jihuai [1 ,3 ]
机构
[1] Huaqiao Univ, Coll Mat Sci & Engn, Xiamen 361021, Peoples R China
[2] Huaqiao Univ, Coll Chem Engn, Xiamen 361021, Peoples R China
[3] Huaqiao Univ, Minist Educ, Engn Res Ctr Environm Friendly Funct Mat, Xiamen 361021, Peoples R China
基金
中国国家自然科学基金;
关键词
Perovskites solar cells; Hysteresis effect; KSCN; Power conversion efficiency; ORGANOMETAL TRIHALIDE PEROVSKITE; HALIDE PEROVSKITES; HYSTERESIS; EFFICIENT; DEPOSITION; STABILITY; MIGRATION; IMPACT; SIZE;
D O I
10.1016/j.orgel.2018.09.040
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Conventional perovskites solar cells have been afflicted with serious hysteresis effect, resulting in difficult to accurate the real power conversion efficiency of devices. Here, an additive of KSCN was applied to enhance the crystallization of perovskite crystals, increased the perovskite grain size, reduced the density of defects, led to a high-quality thin film. Correspondingly, devices with a power conversion efficiency of 19.23% and fill factor of 75.08% under AM 1.5G 100 mW cm(-2) irradiation were achieved. In comparison with typical devices, these solar cells showed improved photovoltaic performance, stability, reproducibility, carrier mobility and lower hysteresis effect, which was attributed to the high-quality thin film. Our work demonstrated a facile and effective approach for fabricating solar cells with no-hysteresis and high-performance towards commercialization.
引用
收藏
页码:207 / 215
页数:9
相关论文
共 42 条
[1]   Maximizing and stabilizing luminescence from halide perovskites with potassium passivation [J].
Abdi-Jalebi, Mojtaba ;
Andaji-Garmaroudi, Zahra ;
Cacovich, Stefania ;
Stavrakas, Camille ;
Philippe, Bertrand ;
Richter, Johannes M. ;
Alsari, Mejd ;
Booker, Edward P. ;
Hutter, Eline M. ;
Pearson, Andrew J. ;
Lilliu, Samuele ;
Savenije, Tom J. ;
Rensmo, Hakan ;
Divitini, Giorgio ;
Ducati, Caterina ;
Friend, Richard H. ;
Stranks, Samuel D. .
NATURE, 2018, 555 (7697) :497-+
[2]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[3]   Eliminating J-V hysteresis in perovskite solar cells via defect controlling [J].
Chen, Wei ;
Sun, Kuan ;
Ma, Chaoyan ;
Leng, Chongqian ;
Fua, Jiehao ;
Hu, Lijun ;
Li, Meng ;
Wang, Ming ;
Zang, Zhigang ;
Tang, Xiaosheng ;
Shi, Haofei ;
Lu, Shirong .
ORGANIC ELECTRONICS, 2018, 58 :283-289
[4]   Impact of microstructure on local carrier lifetime in perovskite solar cells [J].
deQuilettes, Dane W. ;
Vorpahl, Sarah M. ;
Stranks, Samuel D. ;
Nagaoka, Hirokazu ;
Eperon, Giles E. ;
Ziffer, Mark E. ;
Snaith, Henry J. ;
Ginger, David S. .
SCIENCE, 2015, 348 (6235) :683-686
[5]   Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals [J].
Dong, Qingfeng ;
Fang, Yanjun ;
Shao, Yuchuan ;
Mulligan, Padhraic ;
Qiu, Jie ;
Cao, Lei ;
Huang, Jinsong .
SCIENCE, 2015, 347 (6225) :967-970
[6]  
Green MA, 2014, NAT PHOTONICS, V8, P506, DOI [10.1038/NPHOTON.2014.134, 10.1038/nphoton.2014.134]
[7]   Additive engineering for high-performance room-temperature-processed perovskite absorbers with micron-size grains and microsecond-range carrier lifetimes [J].
Han, Qiwei ;
Bai, Yusong ;
Liu, Jie ;
Du, Ke-zhao ;
Li, Tianyang ;
Ji, Dong ;
Zhou, Yihao ;
Cao, Changyong ;
Shin, Donghyeop ;
Ding, Jie ;
Franklin, Aaron D. ;
Glass, Jeffrey T. ;
Hu, Jinsong ;
Therien, Michael J. ;
Liu, Jie ;
Mitzi, David B. .
ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (11) :2365-2371
[8]   Compositional engineering of perovskite materials for high-performance solar cells [J].
Jeon, Nam Joong ;
Noh, Jun Hong ;
Yang, Woon Seok ;
Kim, Young Chan ;
Ryu, Seungchan ;
Seo, Jangwon ;
Seok, Sang Il .
NATURE, 2015, 517 (7535) :476-+
[9]   Planar-Structure Perovskite Solar Cells with Efficiency beyond 21% [J].
Jiang, Qi ;
Chu, Zema ;
Wang, Pengyang ;
Yang, Xiaolei ;
Liu, Heng ;
Wang, Ye ;
Yin, Zhigang ;
Wu, Jinliang ;
Zhang, Xingwang ;
You, Jingbi .
ADVANCED MATERIALS, 2017, 29 (46)
[10]   Effective control of crystal grain size in CH3NH3PbI3 perovskite solar cells with a pseudohalide Pb(SCN)2 additive [J].
Kim, Mi Kyung ;
Jeon, Taewoo ;
Park, Hyung Il ;
Lee, Ju Min ;
Nam, Soo Ah ;
Kim, Sang Ouk .
CRYSTENGCOMM, 2016, 18 (32) :6090-6095