Tert-butyl nitrite: a metal-free radical initiator for aerobic cleavage of benzylic C=C bonds in compressed carbon dioxide

被引：56

作者：

Miao, Cheng-Xia ^{[1
]}

Yu, Bing

He, Liang-Nian

机构：

[1] Nankai Univ, State Key Lab, Tianjin 300071, Peoples R China

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 03期

基金：

中国国家自然科学基金;

关键词：

STEP ALKENE CLEAVAGE; CATALYTIC OXIDATIONS; HYDROGEN-PEROXIDE; OLEFINS;

D O I：

10.1039/c0gc00676a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tert-butyl nitrite easily releasing alkoxyl radical and NO in combination with compressed CO2 under metal free condition was applied to efficiently and selectively initiate aerobic cleavage of benzylic C=C bonds. Notably, compressed CO2 in this study not only provides a safe reaction environment but also tunes the selectivity.

引用

页码：541 / 544

页数：4

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