Preparation and lithium storage properties of active carbon-CNT/sulfur composite

被引:8
作者
Xiao Jianrong [1 ]
Zhao Hang [1 ]
Jiang Aihua [1 ]
Wang Hongzhe [1 ]
Li Yanwei [2 ]
机构
[1] Guilin Univ Technol, Coll Sci, Guilin 541004, Peoples R China
[2] Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Peoples R China
基金
美国国家科学基金会;
关键词
CNT; Activated carbon; Lithium-sulfur battery; Cathode materials; SULFUR CATHODE; PERFORMANCE; NANOTUBES; BATTERIES; BINDER;
D O I
10.1007/s11581-014-1297-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Activated carbon was prepared with active carbon and carbon nanotubes (CNTs) as carriers of sulfur lithium-sulfur battery anode. The preparation was performed by sealing and heating molten lithium-sulfur batteries with different ratios of CNT, which was the positive active material. X-ray diffraction (XRD) pattern showed that composite material had more amorphous structure; the sample of C/CNT ratio of 3:1 exhibited the strongest amorphous, indicating that elemental sulfur was scattered into the pores of the carbon materials. Scanning electron microscopy showed that CNT was evenly dispersed into the activated carbon/sulfur composite materials in the anode material, forming a 3D conductive structure. The discharge specific capacity of the composite test exhibited that a small amount of CNT improved the discharge specific capacity of the anode material to active material for the preparation of activated carbon. The discharge specific capacity of CNT with 2:2 ratio was up to 1371.1 mAh/g. After the first 50 cycles, the discharge specific capacity could be stabilized at 687.3 mAh/g.
引用
收藏
页码:1241 / 1246
页数:6
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