Potassium fluoride on alumina: A convenient synthesis of O-alkyl methyldithiocarbonates. Pyrolysis of O-benzyl-S-methyldithiocarbonates

被引：10
作者：
Villemin, D
Hachemi, M
机构：
[1] Ecl. Natl. Sup. d'Ing. de Caen, I.S.M.R.A., Grp. Catalyse et Modélisation
来源：
SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 13期
关键词：
D O I：
10.1080/00397919608004557
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Xanthates were easily prepared by adsorption of alcohol on KF-Al2O3 followed by treatment of carbon disulfide and iodomethane at room temperature. Pyrolysis of benzyl xanthate affords to a complex mixture of products. A radical process was proposed to explain the nature of products obtained.
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页码：2449 / 2459
页数：11
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