α,β- and β,γ-Unsaturated Phosphonium Salts in Reactions with Halogenating Agents

被引：1

作者：

Ovakimyan, M. Zh. ^{[1
]}

Pogosyan, A. S. ^{[1
]}

Movsisyan, M. L. ^{[1
]}

Indzhikyan, M. G. ^{[1
]}

Tamazyan, R. A. ^{[2
]}

Aivazyan, A. G. ^{[2
]}

机构：

[1] Natl Acad Sci Armenia, Inst Organ Chem, Yerevan 375091, Armenia

[2] Natl Acad Sci Armenia, Ctr Invest Mol Struct, Yerevan 375091, Armenia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2010年 / 80卷 / 11期

关键词：

General Chemistry; Bromine; Phosphonium Salt; Anhydrous Diethyl Ether; Salt Versus;

D O I：

10.1134/S1070363210110046

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 1,4-bisphosphonium salts containing common buta-1,3-dienylene group with the halogenating agenst such as halogens and copper halides is studied. It was found than in all the cases instead of the expected products of the 1,2-or 1,4-addition to the above-mentioned salts the adducts with complex anions were formed quantitatively. According to the X-ray studies of bis(tributylphosphonio)buta-1,3-dienotribromocuprate the positive charge on phosphorus is compensated with the complex [Cu2Br6](2-) anion.

引用

页码：2243 / 2248

页数：6

共 50 条

[21] REACTIONS OF ELECTROPHILES WITH PHOSPHONIUM SALTS IN ABSENCE OF AUXILIARY BASES
SCHIEMEN.GP
BECKER, J
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1969, 8 (11) : 921 - &
[22] Reactions of acylsulfonium salts with unsaturated hydrocarbons
Nenajdenko, VG
Lebedev, MV
Balenkova, ES
TETRAHEDRON, 2001, 57 (43) : 9017 - 9024
[23] THE REACTIONS OF ORGANIC DERIVATIVES OF ELEMENTS CAPABLE OF VALENCY-SHELL EXPANSION .2. UNSATURATED QUATERNARY PHOSPHONIUM SALTS
ROTHSTEIN, E
SAVILLE, RW
HORN, PE
JOURNAL OF THE CHEMICAL SOCIETY, 1953, (DEC): : 3994 - 4004
[24] Reactions of gem-Difluorinated Phosphonium Salts Induced by Light
Panferova, Liubov I.
Tsymbal, Artem V.
Levin, Vitalij V.
Struchkova, Marina I.
Dilman, Alexander D.
ORGANIC LETTERS, 2016, 18 (05) : 996 - 999
[25] STABLE QUASI-PHOSPHONIUM SALTS IN REACTIONS OF ALLENYLPHOSPHONATES WITH SULFENYLCHLORIDES
KHUSAINOVA, NG
NAUMOVA, LV
BERDNIKOV, EA
PUDOVIK, AN
ZHURNAL OBSHCHEI KHIMII, 1984, 54 (06): : 1424 - 1425
[26] REACTIONS OF DIALKYLPHOSPHINO-SUBSTITUTED PHOSPHORANE-PHOSPHONIUM SALTS
MASTRYUKOVA, TA
ALADZHEVA, IM
LEONTEVA, IV
SVOREN, VA
PETROVSKII, PV
KABACHNIK, MI
ZHURNAL OBSHCHEI KHIMII, 1977, 47 (11): : 2449 - 2454
[27] Asymmetric Strecker Reactions Catalyzed by Thiourea Phosphonium and Ammonium Salts
Wang, Hongyu
Wang, Kaiye
Ren, Yanfei
Li, Na
Tang, Bo
Zhao, Gang
ADVANCED SYNTHESIS & CATALYSIS, 2017, 359 (11) : 1819 - 1824
[28] A facile synthesis of ω-bromo-diene via solid/liquid transferred Wittig reactions ω-bromobutyltriphenyl phosphonium salts with α,β-unsaturated aldehydes
Shi, DQ
Chen, RY
CHINESE CHEMICAL LETTERS, 1999, 10 (11) : 911 - 914
[29] NEW SYNTHESES OF VINYL SULFIDES AND UNSATURATED NITRILES VIA QUATERNARY PHOSPHONIUM SALTS
KUMAMOTO, T
HOSOI, K
MUKAIYAM.T
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1968, 41 (11) : 2742 - +
[30] Photochemical Synthesis of Polycyclic Phosphonium Salts as Efficient Anticancer and Antibacterial Agents
Li, Jianqing
Zhuang, Zeyan
Dong, Xiaobin
Zhao, Zujin
Tang, Ben Zhong
AGGREGATE, 2024,

← 1 2 3 4 5 →