α,β- and β,γ-Unsaturated Phosphonium Salts in Reactions with Halogenating Agents

被引：1
|
作者：
Ovakimyan, M. Zh. [1 ]
Pogosyan, A. S. [1 ]
Movsisyan, M. L. [1 ]
Indzhikyan, M. G. [1 ]
Tamazyan, R. A. [2 ]
Aivazyan, A. G. [2 ]
机构：
[1] Natl Acad Sci Armenia, Inst Organ Chem, Yerevan 375091, Armenia
[2] Natl Acad Sci Armenia, Ctr Invest Mol Struct, Yerevan 375091, Armenia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2010年 / 80卷 / 11期
关键词：
General Chemistry; Bromine; Phosphonium Salt; Anhydrous Diethyl Ether; Salt Versus;
D O I：
10.1134/S1070363210110046
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of 1,4-bisphosphonium salts containing common buta-1,3-dienylene group with the halogenating agenst such as halogens and copper halides is studied. It was found than in all the cases instead of the expected products of the 1,2-or 1,4-addition to the above-mentioned salts the adducts with complex anions were formed quantitatively. According to the X-ray studies of bis(tributylphosphonio)buta-1,3-dienotribromocuprate the positive charge on phosphorus is compensated with the complex [Cu2Br6](2-) anion.
引用
收藏
页码：2243 / 2248
页数：6
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